| 207677-07-4

• CAS: 207677-07-4
• 化学式: C₂₈H₄₂NO₄PRu
• 分子量: 588.69
• InChiKey: FYROLVFJFQEISQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and reactivity of η6-arene ruthenium anilide complexes

  摘要：

  The compounds, (eta(6)-C6Me6)Ru(PMe3)(R)(NR'R"); (R=Ph, R'=H, R"=Ph, 3; R=Me, R'=H, R"=Ph, 4; R=Ph, R'=H; R"=p-tol, 5; R=Me, R'=Me, R"=Ph, 6) are synthesized through the interaction of (eta(6)-C6Me6)Ru(PMe3)(R)(I) and the corresponding anilide salt, KNR'R" in THF at low temperature. The reactions between these complexes and the unsaturated electrophilic reagents, CO2 and dimethylacetylene dicarboxylate (DMAD) have been described. The typical reaction involves net insertion of the electrophile into the Ru anilide bond. Complex 6 reacts with H2O giving the hydroxide complex, 11, which reacts with CO2 giving the bicarbonato complex, 12. The X-ray crystal structure of 3 is reported. Compound 3 crystallizes in the monoclinic space group, P2(1)/n, a = 12.013(2) Angstrom, b = 16.700(3) Angstrom, c = 12.414(1) Angstrom, beta = 97.35(2), V = 2470.0(7) Angstrom(3) and Z = 4. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00373-2
• 作为产物：
  描述：

  carbanide;1,2,3,4,5,6-hexamethylbenzene;phenylazanide;ruthenium(2+);trimethylphosphane 、 丁炔二酸二甲酯 以 四氢呋喃 为溶剂， 以32%的产率得到
  参考文献：
  名称：

  Synthesis and reactivity of η6-arene ruthenium anilide complexes

  摘要：

  The compounds, (eta(6)-C6Me6)Ru(PMe3)(R)(NR'R"); (R=Ph, R'=H, R"=Ph, 3; R=Me, R'=H, R"=Ph, 4; R=Ph, R'=H; R"=p-tol, 5; R=Me, R'=Me, R"=Ph, 6) are synthesized through the interaction of (eta(6)-C6Me6)Ru(PMe3)(R)(I) and the corresponding anilide salt, KNR'R" in THF at low temperature. The reactions between these complexes and the unsaturated electrophilic reagents, CO2 and dimethylacetylene dicarboxylate (DMAD) have been described. The typical reaction involves net insertion of the electrophile into the Ru anilide bond. Complex 6 reacts with H2O giving the hydroxide complex, 11, which reacts with CO2 giving the bicarbonato complex, 12. The X-ray crystal structure of 3 is reported. Compound 3 crystallizes in the monoclinic space group, P2(1)/n, a = 12.013(2) Angstrom, b = 16.700(3) Angstrom, c = 12.414(1) Angstrom, beta = 97.35(2), V = 2470.0(7) Angstrom(3) and Z = 4. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00373-2