| 1410111-11-3

• CAS: 1410111-11-3
• 化学式: C₂₆H₃₁Br₂N₃Ni
• 分子量: 604.05
• InChiKey: IXORHWLTFOOZIW-BFOWFUBKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2,6-diisopropylphenyl)acetimidoyl chloride 在 三乙胺 作用下， 以 乙二醇二甲醚 、 甲苯 为溶剂， 反应 6.0h， 生成
  参考文献：
  名称：

  Synthesis, spectroscopic and structural characterization of Co(II), Ni(II) and Cu(II) complexes of substituted 2-pyridyl amine based [N,N] chelating ligand

  摘要：

  The reaction of N-benzylaminopyridine with the imidoylchloride of N-(2,6-iPr(2)C(6)H(3))acetamide in the presence of Et3N affords a new neutral INN] chelating ligand, (PhCH2)N(2-pyridyl)C[(Me)(=-N-2,6-iPr(2)C(6)-H-3)] (L). The reaction of equimolar quantities of L with Cu(NO3)(2), CuCl2 and NiBr2, respectively, in DCM, acetonitrile and DME yields the corresponding mononuclear complexes L center dot Cu(NO3)(2) (1), L center dot CuCl2 (2) and L center dot NiBr2 (3). Whereas, the reaction of L with CoCl2 center dot 6H(2)O leads to the formation of [HL center dot CoCl3] (4) with pyridine nitrogen coordinated to cobalt. Solid state structure of L and compounds 1-4 have been investigated by single crystal X-ray structural analysis. The ligand L shows the E-anti arrangement in the solid state and its mononuclear complex 1 shows six coordinated Cu in a quasi square planar geometry with two long distanced donors; complexes 2 and 3 show distorted tetrahedral arrangement of the substituents around metal ions. Interestingly, the solid state structure of complex 4 reveals C-H center dot center dot center dot Cl intra-molecular hydrogen bonding and N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl inter-molecular hydrogen bonds. These hydrogen bonding interactions in complex 4 facilitate the formation of an extended 2D network structure. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.019