| 76879-87-3

• CAS: 76879-87-3
• 化学式: C₁₃H₆O₁₀Ru₃
• 分子量: 625.395
• InChiKey: SPHAZEOJPANBQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 三甲硅基丙炔醇 以 苯 为溶剂， 以7%的产率得到(μ-H)Ru3(CO)9(μ3-η3-C3H3)
  参考文献：
  名称：

  Formation of an allylic cluster in the reactions of [Ru3(CO)12] with diethylamino-propyne and trimethylsilyl propargyl alcohol. Crystal structure of [(μ-H)Ru3(CO)9(μ3-η3-C3H3)]

  摘要：

  The title complex (mu-H)Ru-3(CO)(9)(mu(3)-eta(3)-C3H3) has been obtained following two different reaction pathways: one is the deamination of diethylaminopropyne, HCdropCCH(2)NEt(2), in the presence of Ru-3(CO)(12) under thermal conditions. The other is the reaction of trimethylsilylpropargyl alcohol, (HO)H(2)CCdropC(SiMe3) (TSPA), with Ru-3(CO)(12). The complex is obtained both under thermal conditions and in the reaction of the carbonyl with TSPA in CH3OH/KOH (followed by acidification). Other reaction products, deriving from the loss of Me3Si and of HCHO fragments from TSPA, have also been characterized. Complex (mu-H)Ru-3(CO)(9)(mu(3)-eta(3)-C3H3) has been spectroscopically characterized and its crystal structure was determined by an X-ray analysis. An isosceles triangle of Ru atoms with an edge bridged by an H atom, is coordinated by an allylic moiety sigma-bonded to two Ru atoms and pi-interacting with the third Ru atom. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(03)00094-9

文献信息

• Trinuclear osmium and ruthenium clusters containing ligands formed by dehydration and rearrangement of 1,4-dihydroxybut-2-yne
  作者：Silvio Aime、Antonio Tiripicchio、Marisa Tiripicchio Camellini、Antony J. Deeming

  DOI：10.1021/ic50221a020

  日期：1981.7