1-(4-hydroxybutyl)-1'-(3-butenyl) ferrocene | 1588424-83-2

• 英文名称: 1-(4-hydroxybutyl)-1'-(3-butenyl) ferrocene
• CAS: 1588424-83-2
• 化学式: C₁₈H₂₄FeO
• 分子量: 312.235
• InChiKey: CDURMRALQWGNJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1'-bis(4-chlorobutyl)ferrocene 在 potassium hydroxide 作用下， 以 二甲基亚砜 为溶剂， 以58%的产率得到1,1'-bis(3-butenyl)ferrocene
  参考文献：
  名称：

  Synthesis, characterization and electrochemical properties of novel trinuclear ferrocenyl based organosilane compounds

  摘要：

  Some trinuclear ferrocenyl based organosilane compounds were synthesized by hydrosilylation reaction of [4-(ethylferrocenyl)butyl]dimethylsilane and (4-ferrocenylbutyl)dimethylsilane with bisalkenylferrocene derivatives, in the presence of the Karstedt catalyst at room temperature. In addition a simple method for the preparation of 1,1'-bis(3-butenyl)alkylferrocenes from 1,1'-bis(4-chlorobutyl)alkylferrocenes under mild conditions was developed. H-1 and C-13 NMR, FT-IR, GC MS, CHN analysis, atomic absorbtion spectroscopy supported the predicted structure of the products. The electrochemical behavior of synthesized compounds was studied by cyclic voltammetry in CH3CN/0.1 M LiClO4 utilizing a glasse carbon working electrode. The relationship between the peak currents and the square root of the scan rate, showed that the redox process is diffusion limited. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.02.001