[PtMe(2,9-Me2-1,10-phenathroline)(η(1),η(2)-CH(CO2Et)O2CCH=CHCO2Me)] | 244128-56-1

• 英文名称: [PtMe(2,9-Me2-1,10-phenathroline)(η(1),η(2)-CH(CO2Et)O2CCH=CHCO2Me)]
• CAS: 244128-56-1；244185-11-3
• 化学式: C₂₄H₂₆N₂O₆Pt
• 分子量: 633.56
• InChiKey: UHTUEOVXTLKCNZ-ZGVDEOGJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  重氮乙酸乙酯 、 [Pt(CH3)(H2O)(2,9-dimethyl-1,10-phenanthroline)(dimethyl maleate)]BF4 BF4(1-)*C21H25N2O5Pt(1+), yellow 以 甲醇 为溶剂， 以95%的产率得到[PtMe(2,9-Me2-1,10-phenathroline)(η(1),η(2)-CH(CO2Et)O2CCH=CHCO2Me)]
  参考文献：
  名称：

  First Coordinatively Saturated Carbene Complexes of Platinum(II):  Synthesis, Structure, and Reactivity

  摘要：

  Coordinatively saturated carbene complexes of platinum(II) have been obtained by oxidative addition of [ClCH=NMe2]Cl to Pt(0) precursors. The cationic products of general formula [PtCl(CHNMe2)(N,N-chelate)(olefin)]Cl have been characterized through NMR spectroscopy and for [PtCl(CHNMe2)(2,9-Me-2-1,10-phen)(Z-MeO2CCH=CHCO2Me)]Cl by X-ray diffractometry. The latter species reacts with nucleophiles affording dimethylformamide and the corresponding Pt(0) precursor [Pt(2,9-Me-2-1,10-phen)(Z-MeO2CCH=CHCO2Me)]. Attempts to obtain related complexes containing carbene groups Pt=CHY without a heteroatom in alpha-position (Y = CO2Et, CO2NMe2, CN) have led to the isolation of complexes of formula [PtR(dmphen){eta(1),eta(2)-CH(Y)O2CCH=CHCO2Me}] (R = Me, Ph), Formally derived fi om an intrasnolecular nucleophilic addition to a carbene intermediate. The X-ray structure of a representative product, [PtMe(dmphen){eta(1),eta(2)-CH(CO2Et)O2CCH=CHCO2Me}], is reported.

  DOI：

  10.1021/om990240r