(HC((CMe)(2,6-iPr2C6H3N))2)GaF2 | 879329-57-4

• 英文名称: (HC((CMe)(2,6-iPr2C6H3N))2)GaF2
• CAS: 879329-57-4
• 化学式: C₂₉H₄₁F₂GaN₂
• 分子量: 525.378
• InChiKey: ADEBXOWQVAOCSG-KSWNCPITSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Dipp2nacnacGaI2 、 三甲基氟锡烷 以 苯 为溶剂， 以90%的产率得到(HC((CMe)(2,6-iPr2C6H3N))2)GaF2
  参考文献：
  名称：

  Syntheses, Characterization, and X-ray Crystal Structures of β-Diketiminate Group 13 Hydrides, Chlorides, and Fluorides

  摘要：

  A series of organometallic compounds of group 13 metals supported by the sterically encumbered beta-diketiminate ligand containing hydrides, fluorides, chlorides, and bromide have been synthesized and structurally characterized. The synthetic strategy applied utilizes halide metathesis and reduction of metal chlorides to the corresponding hydrides. Thus, the reaction of (LLiOEt2)-O-. with MeMCl2 affords LM(Me)Cl (M = Al (1), Ga (2), In (3)) and LGaBr2 (4) with GaBr3. Reduction of LGa(Me)Cl with (LiHBEt3)-B-. leads to the formation of LGa(Me)H (10). Synthesis of LGaH2 (12) has been accomplished by reacting LGal(2) (8) with (LiHBEt3)-B-.. LAl(Me)Cl (1) and LAlH2 (6) have been converted to LAl(Me)F (5) and LAlF2 (7), respectively. The former was obtained in a reaction of LAI(Me)Cl with Me3SnF while the latter was isolated in a reaction of LAlH2 with (BF3OEt2)-O-.. Similarly reaction of LGal(2) (8) with Me3SnF affords LGaF2 (9). Compounds reported herein have been characterized by elemental analyses, IR, NMR, El-MS, and single-crystal X-ray diffraction techniques.

  DOI：

  10.1021/ic0517826