(1R,2R,5R,6R,7S)-6-Methyl-6-(2,2,2-trifluoro-ethoxy)-tricyclo[3.2.0.0^2,7]heptane-1-carbonitrile | 81898-02-4

• 英文名称: (1R,2R,5R,6R,7S)-6-Methyl-6-(2,2,2-trifluoro-ethoxy)-tricyclo[3.2.0.0^2,7]heptane-1-carbonitrile
• CAS: 81898-02-4
• 化学式: C₁₁H₁₂F₃NO
• 分子量: 231.218
• InChiKey: ZEIZHMHDPSRMSY-ZOZBQHSOSA-N

反应信息

• 作为产物：
  描述：

  2,2,2-三氟乙醇 、 Toluene-4-sulfonic acid (1S,4R,7R)-7-cyano-2-methyl-bicyclo[2.2.1]hept-2-en-7-yl ester 以26%的产率得到(1S,4R,7R)-2-Methyl-7-(2,2,2-trifluoro-ethoxy)-bicyclo[2.2.1]hept-2-ene-7-carbonitrile
  参考文献：
  名称：

  Magnification of neighboring group participation in the solvolytic generation of carbocations through the placement of an electron-withdrawing substituent on the incipient cationic center

  摘要：

  DOI：

  10.1021/ja00377a043