| 206862-38-6

• CAS: 206862-38-6
• 化学式: Br₉Re₂*C₂₄H₂₀P
• 分子量: 1430.95
• InChiKey: DQCVMDVCVHLMMI-UHFFFAOYSA-E

反应信息

• 作为产物：
  描述：

  、 三溴化硼 以 二氯甲烷 为溶剂， 以75%的产率得到
  参考文献：
  名称：

  Darstellung und Kristallstrukturen von (Ph3PNPPh3)2[Re2Br10] und (Ph4P)[Re2Br9]

  摘要：

  Depending on the molar ratio by reaction of [n-Bu4N](2)[ReBr6] With the Lewis acid BBr3 in dichloromethane the bioctahedral complexes [n-Bu4N](2)[Re2Br10] and [n-Bu4N][Re2Br9] are formed. The X-ray structure determination on (Ph3PNPPh3)(2)[Re2Br10] (monoclinic, space group C 2/c, a = 20.007(4), b = 15.456(5), c = 24.695(4) Angstrom, beta = 107.53(2)degrees, Z = 4) reveals a centrosymmetric edge-sharing complex anion with approximate D-2h symmetry and mean terminal and bridging Re-Br bond lengths of 2.453 (equatorial), 2.482 (axial) and 2.591 Angstrom, respectively, and a Re-Re distance of 3.880 Angstrom. (Ph4P)[Re2Br9] (triclinic, space group , a = 11.062(2), b = 12.430(3), c = 13.163(5) Angstrom, alpha = 72.94(2), beta = 68.47(2), gamma = 82.09(2)degrees, Z = 2) contains a confacial bioctahedral anion with nearly D-3h symmetry and mean terminal and bridging Re-Br distances of 2.460 and 2.536 Angstrom, respectively, and a Re-Re distance of 2.780 Angstrom.

  DOI：

  10.1002/(sici)1521-3749(199804)624:4<578::aid-zaac578>3.0.co;2-9