4-amino-4'-ferrocenyl-2,3'-dimethylazobenzene | 220082-14-4

• 英文名称: 4-amino-4'-ferrocenyl-2,3'-dimethylazobenzene
• 英文别名: 4-amino-4'-ferocenyl-2,3'-dimethylazobenzene
• CAS: 220082-14-4
• 化学式: C₂₄H₂₃FeN₃
• 分子量: 409.314
• InChiKey: UGWKYFAAPRENNE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  4-amino-4'-ferrocenyl-2,3'-dimethylazobenzene 、 2-甲基-4-硝基-1-亚硝基苯 以 溶剂黄146 为溶剂， 以35%的产率得到4'-ferrocenyl-2,3'-dimethyl-4-(2-methyl-4-nitrophenylazo)azobenzene* 0.1 CH2Cl2
  参考文献：
  名称：

  含钼或钨单亚硝酰基氧化还原中心的非线性光学材料：二芳族偶氮衍生物

  摘要：

  已制备以下化合物：[M（NO）L（X）n {EC 6 H 3（R-3）[N NC 6 H 3（R'-3）（R''-4）-4]} 2 – n ] [L =三（3,5-二甲基吡唑基）氢硼酸盐；R“=（η 5 -C 5 H ^ 4）的Fe（η 5 -C 5 H ^ 5）中，E = O，R = R'= H，M =钼，X = Cl或I，ñ = 0或1; E ＝ NH，R ＝ R′＝ H，n＝ 1，M ＝ Mo或W，X ＝ Cl。E ＝ NH，R ＝ Me，R′＝ H，n＝ 1，M ＝ Mo，X ＝ F，Cl，Br，I或OC 6 H 11；E ＝ NH，R ＝ Me，R ＝ H，n＝ 1，M ＝ Mo，X ＝ F，Cl，Br，I或OC 6 H 11。M = W，X = Cl；E = NH，R = R′= Me，n= 1，M = Mo，X = Cl或I；M = W，X = Cl；R” ＝ NMe 2，E

  DOI：

  10.1039/dt9940003427
• 作为产物：
  描述：

  sodiumsulfide nonahydrate 、 4-nitro-2-methyl-3'-methyl-4'-ferrocenylazobenzene 以 乙醇 为溶剂， 以94%的产率得到4-amino-4'-ferrocenyl-2,3'-dimethylazobenzene
  参考文献：
  名称：

  含钼或钨单亚硝酰基氧化还原中心的非线性光学材料：二芳族偶氮衍生物

  摘要：

  已制备以下化合物：[M（NO）L（X）n {EC 6 H 3（R-3）[N NC 6 H 3（R'-3）（R''-4）-4]} 2 – n ] [L =三（3,5-二甲基吡唑基）氢硼酸盐；R“=（η 5 -C 5 H ^ 4）的Fe（η 5 -C 5 H ^ 5）中，E = O，R = R'= H，M =钼，X = Cl或I，ñ = 0或1; E ＝ NH，R ＝ R′＝ H，n＝ 1，M ＝ Mo或W，X ＝ Cl。E ＝ NH，R ＝ Me，R′＝ H，n＝ 1，M ＝ Mo，X ＝ F，Cl，Br，I或OC 6 H 11；E ＝ NH，R ＝ Me，R ＝ H，n＝ 1，M ＝ Mo，X ＝ F，Cl，Br，I或OC 6 H 11。M = W，X = Cl；E = NH，R = R′= Me，n= 1，M = Mo，X = Cl或I；M = W，X = Cl；R” ＝ NMe 2，E

  DOI：

  10.1039/dt9940003427

文献信息

• Second-Order Nonlinear Performance of Poly(methyl methacrylate) Films with Dispersed Donor−Acceptor Organobimetallic Compounds
  作者：Carolina López-Garabito、Jose A. Campo、Jose V. Heras、Mercedes Cano、Gema Rojo、Fernando Agulló-López

  DOI：10.1021/jp982764v

  日期：1998.12.1

  New organobimetallic Mo/Fe compounds of the type [Mo(Tp(An))(NO)(Cl)(Y-pi-bridge)(Fc)] Tp(An) = hydrotris-(3-p-methoxyphenylpyrazol-1-yl)borate; Fc = (eta(5)-C5H4)Fe(eta(5)-C5H5); Y = NH (1), O (5), bridge = C6H4; Y NH, bridge C6H3R-N=N-C6H3R' [R = R' H (2); R = CH3, R' = H (3); R = R' = CH3 (4); Y = NH, bridge = C6H4-CH=CH-C6H4 (6)} have been synthesized and characterized. The second-harmonic generation yield of corona-poled spin-coated films of poly(methyl methacrylate) containing these compounds has been investigated. The three nonzero components, chi(31)((2)), chi(15)((2)), and chi(33)((2)), of the susceptibility tensor have been measured. chi 31(2) is the highest component at different with linear (one-dimensional) molecules where chi(33)((2)) = 3 chi(31)((2)) Moreover, Kleinman symmetry (chi(31)((2)) = chi(15)((2)) is not obeyed. These results have been discussed on the basis of a low-lying charge-transfer optical transition that has a perpendicular component to the permanent dipole moment. From the measured chi((2)) components, the molecular hyperpolarizabilities beta(33), beta(15), and beta(31) have been estimated under the assumption of thermal equilibrium under the poling field. On the ether hand, the role of diverse bridging structures on the susceptibilities, including different lengths (diarylazoamide vs anilide), as well as methyl substituents and linking (C-C vs N=N) groups, has been evaluated. Moreover, the acceptor [Mo(Tp(An))(NO)(Cl)(Y)] and nitro groups have been compared in compounds having the same ferrocenyl donor group and polarizable bridging system. chi(31)((2)) susceptibilities are significant in most cases, and values as high as 6.6 x 10(-9) esu have been obtained for the 4-nitro-4'-ferrocenylstilbene compound.