| 350513-59-6

• CAS: 350513-59-6
• 化学式: C₃₆H₈₆Al₂F₄Li₂O₅Si₆
• 分子量: 911.428
• InChiKey: ADQWVZLQDCQGCN-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  四氢呋喃 、 [(SiMe3)3CAlF2]3 、 lithium oxide 以 四氢呋喃 为溶剂， 以68%的产率得到
  参考文献：
  名称：

  Synthesis and Structures of [((Me₃Si)₃CAlF₂)₂(μ-O)Li₂(THF)₄] and [{Li(Me₃Si)₃CAlF₃(THF)}₃LiF(THF)]

  摘要：

  The synthesis of [((Me3Si)(3)CAlF2)(2)(mu -O)Li-2- (THF)(4)] (1) and [{Li(Me3Si)(3)CAlF3(THF)}(3)LiF(THF)] (2) is reported. Compound 1 was obtained either by the reaction of (Me3Si)(3)CAlMe2. THF and Me3SnF in the presence of Li2O or by the reaction of [(Me3Si)(3)CAlF2](3) and Li2O. 1 is an interesting example of an oxygen- and fluorine-containing alkyl aluminum compound. Complex 2 was prepared by the reaction of (Me3Si)(3)CAlF2. THF with LiOCH(CF3)(2) as an unexpected result that illustrates the variety of possible structures obtainable by the combination of [(Me3Si)(3)CAlF2](3) and LiF.

  DOI：

  10.1021/om0100941