Si(CH2CH2SiMe2CCHCo2(CO)6)4 | 171520-48-2

• 英文名称: Si(CH2CH2SiMe2CCHCo2(CO)6)4
• CAS: 171520-48-2
• 化学式: C₄₈H₄₄Co₈O₂₄Si₅
• 分子量: 1617.24
• InChiKey: ZUVYYUABAYJYEN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  dicobalt octacarbonyl 、 Si(CH2CH2SiMe2C*CH)4 以 petroleum ether 为溶剂， 以84%的产率得到Si(CH2CH2SiMe2CCHCo2(CO)6)4
  参考文献：
  名称：

  Preparation of carbosilane dendrimers with peripheral acetylenedicobalt hexacarbonyl substituents

  摘要：

  The carbosilane dendrimers Si[CH(2)CH(2)SiMe(2)C=CH](4), 1, Si[CH(2)CH(2)SiMe(C=CH)(2)](4), 2, and Si[CH2CH2Si(CH(2)CH(2)SiMe(2)C=CH)(3)](4), 5, have been prepared. Reaction of Co-2(CO)(8) with all the C=CH groups in 1 and 5 gave the corresponding acetylenedicobalt hexacarbonyl complexes. The structure of Si[CH(2)CH(2)SiMe(2)-C2HCo2(CO)(6)](4) was determined in an X-ray diffraction study.

  DOI：

  10.1021/om00011a062