(2-mercaptopyridinato)3TiCl | 226949-83-3

• 英文名称: (2-mercaptopyridinato)3TiCl
• CAS: 226949-83-3
• 化学式: C₁₅H₁₂ClN₃S₃Ti
• 分子量: 413.811
• InChiKey: OJLBFYYOBKLWLG-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2-mercaptopyridinato)3TiCl 以 neat (no solvent) 为溶剂， 生成 dioxide titanium 、 titanium(IV) sulfide
  参考文献：
  名称：

  Synthesis and characterisation of titanium pyridine- and pyrimidine-thiolates and their application as precursors to titanium disulfide

  摘要：

  The reaction of TiCl(4) with pyridine- and pyrimidine-thiol has been investigated. Reaction of TiCl(4) with 3 equiv. of 2-mercaptopyridine and 3 equiv. of tert-butylpyridine in toluene at room temperature resulted in the formation of the tris(pyridine-2-thiolate) complex [TiCl(SC(5)H(4)N)(3)] (1). The related reaction between TiCl(4) with 3 equiv. of 2-mercaptopyrimidine and 3 equiv. of tert-butylpyridine in toluene at room temperature resulted in the isolation of the complex [TiCl(SC(4)H(3)N(2))(3)] (2). Compound 2 has been characterised by X-ray crystallography. Low pressure CVD of 1 and 2 produced brown/gold films of TiS(2)/TiO(2) on glass substrates at 550 and 600 degrees C. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.07.017
• 作为产物：
  描述：

  2-巯基吡啶 、 四氯化钛 在 4-tert-butylpyridine 作用下， 以 甲苯 为溶剂， 以84%的产率得到(2-mercaptopyridinato)3TiCl
  参考文献：
  名称：

  Synthesis and characterisation of titanium pyridine- and pyrimidine-thiolates and their application as precursors to titanium disulfide

  摘要：

  The reaction of TiCl(4) with pyridine- and pyrimidine-thiol has been investigated. Reaction of TiCl(4) with 3 equiv. of 2-mercaptopyridine and 3 equiv. of tert-butylpyridine in toluene at room temperature resulted in the formation of the tris(pyridine-2-thiolate) complex [TiCl(SC(5)H(4)N)(3)] (1). The related reaction between TiCl(4) with 3 equiv. of 2-mercaptopyrimidine and 3 equiv. of tert-butylpyridine in toluene at room temperature resulted in the isolation of the complex [TiCl(SC(4)H(3)N(2))(3)] (2). Compound 2 has been characterised by X-ray crystallography. Low pressure CVD of 1 and 2 produced brown/gold films of TiS(2)/TiO(2) on glass substrates at 550 and 600 degrees C. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.07.017