[Si(2,2′-bipyridine)2(dipyridocatecholate)](I−)(I3−) | 1443360-11-9

• 英文名称: [Si(2,2′-bipyridine)2(dipyridocatecholate)](I−)(I3−)
• 英文别名: [Si(2,2′-bipyridine)₂(dipyridocatecholate)](I^-)(I₃^-)
• CAS: 1443360-11-9
• 化学式: C₃₂H₂₂N₆O₂Si*I*I₃
• 分子量: 1058.27
• InChiKey: ZECKUGKEIQFOIJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 [Si(2,2′-bipyridine)2(dipyridocatecholate)](I−)(I3−) 以 水 、 丙酮 为溶剂， 生成 [Si(2,2′-bipyridine)₂(dipyridocatecholate)](PF₆)₂
  参考文献：
  名称：

  Synthesis and characterization of a dipyridocatecholate silicon complex

  摘要：

  The reaction of [Si(bpy)(2)I-2]I-2 with 1,10-phenanthroline-5,6-dione followed by metathesis provides various salts of [Si(bpy)(2)(dpcat)](+2) (1, bpy = 2,2'-bipyridine and dpcat = dipyridocatecholate). Recrystallization of [Si(bpy)(2)(dpcat)](ClO4)(2) from an aqueous solution of NaClO4 afforded orange crystals of Na[Si(bpy)(2)(dpcatH)](ClO4)(4)center dot 3H(2)O (2), in which silicon possesses a distorted octahedral geometry. The dipyridocatecholate ligand is coordinated to the silicon through the oxygen atoms, and one of the nitrogen atoms is protonated. Si-29 NMR and ESI-mass spectroscopy indicate [Si(bpy)(2)(dpcat)](+2) maintains its hexacoordinate structure in solution. The complex is stable with respect to hydrolysis, and degassed aqueous solutions luminesce at 410 nm. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.03.031
• 作为产物：
  描述：

  1,10-邻二氮杂菲-5,6-二酮 、 [Si(2,2′-bipyridine)₂I₂]I₂ 在 吡啶 作用下， 以54%的产率得到[Si(2,2′-bipyridine)2(dipyridocatecholate)](I−)(I3−)
  参考文献：
  名称：

  Synthesis and characterization of a dipyridocatecholate silicon complex

  摘要：

  The reaction of [Si(bpy)(2)I-2]I-2 with 1,10-phenanthroline-5,6-dione followed by metathesis provides various salts of [Si(bpy)(2)(dpcat)](+2) (1, bpy = 2,2'-bipyridine and dpcat = dipyridocatecholate). Recrystallization of [Si(bpy)(2)(dpcat)](ClO4)(2) from an aqueous solution of NaClO4 afforded orange crystals of Na[Si(bpy)(2)(dpcatH)](ClO4)(4)center dot 3H(2)O (2), in which silicon possesses a distorted octahedral geometry. The dipyridocatecholate ligand is coordinated to the silicon through the oxygen atoms, and one of the nitrogen atoms is protonated. Si-29 NMR and ESI-mass spectroscopy indicate [Si(bpy)(2)(dpcat)](+2) maintains its hexacoordinate structure in solution. The complex is stable with respect to hydrolysis, and degassed aqueous solutions luminesce at 410 nm. (c) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2013.03.031