2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide dimer | 195210-31-2

• 英文名称: 2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide dimer
• CAS: 195210-31-2
• 化学式: C₃₄H₄₂Br₂Cu₂P₂Si₂
• 分子量: 855.726
• InChiKey: OISMHUFOHXKLEA-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper(ll) bromide 、 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine 以 甲醇 为溶剂， 以45%的产率得到2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide dimer
  参考文献：
  名称：

  Dimeric 2,2-dimethyl-2-silabut-3-enyldiphenylphosphinecopper(I) bromide: a chelating olefinic-phosphine copper(I) complex

  摘要：

  The reaction between CuBr2 and 2,2-dimethyl-2-silabut-3-enyldiphenylphosphine (L-1) in methanol produced the title complex 1; the single crystal X-ray crystal structure of 1 reveals a centrosymmetric dimeric bromo-bridged species, with the copper(I) atoms bound to both the olefin and phosphorus donor sites on the ligands. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00105-8