Nb(η5-C5H4SiMe2-η-N(CH2)2-η-NHMe)Cl3 | 871326-88-4

• 英文名称: Nb(η5-C5H4SiMe2-η-N(CH2)2-η-NHMe)Cl3
• CAS: 871326-88-4
• 化学式: C₁₀H₁₈Cl₃N₂NbSi
• 分子量: 393.617
• InChiKey: MQHUTZBDRYEGDT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Nb(η(5)-C5H4(SiClMe2))Cl4] 、 [Ti(η(5):η(1)-C5H4Si(CH3)2N(CH2)2-η-NH(CH3))Cl2] 以 甲苯 为溶剂， 以10%的产率得到Nb(η5-C5H4SiMe2-η-N(CH2)2-η-NHMe)Cl3
  参考文献：
  名称：

  Cyclopentadienyl-Silyl-Amido Niobium Complexes Prepared by a Transmetalation Reaction Using Ti{η⁵-C₅H₄SiMe₂-η-N(CH₂)₂NRR‘}Cl₂

  摘要：

  Reaction of Ti{eta(5)-C5H4SiMe2-eta-N(CH2)(2)NRR'}Cl-2 with Nb(eta(5)-C5H4SiMe2Cl)Cl-4 affords the tethered heterodinuclear complexes TiCl2{eta(5)-C5H4SiMe2-eta-N(CH2)(2)-K-NRR'}Nb(eta(5)-C5H4SiMe2-Cl)Cl-4, which are thermally unstable in solution and evolve to render an equimolar mixture of Ti(eta(5)-C5H4SiMe2Cl)Cl-3 and the corresponding cyclopentadienyl-amido niobium compounds, Nb{eta(5)-C5H4SiMe2-eta-N(CH2)(2)NRR'}Cl-3. These compounds are straightforwardly obtained from the reaction of Nb(eta(5)-C5H4SiMe2Cl)Cl-4 with 1 equiv of the appropriate diamine, NH2(CH2),-NRR', in the presence of 2 equiv of NEt3, in high yield. In this reaction, the presence of the functional pendant chain plays a central role not only in determining the course of the reaction but also in stabilizing the final product, from both an electronic and a steric point of view. The molecular structure of Nb{eta(5)-C5H4SiMe2-eta-N(CH2)(3)-eta-NH2]Cl-3 has been determined by X-ray diffraction methods.

  DOI：

  10.1021/om0505312