| 946425-67-8

• CAS: 946425-67-8
• 化学式: C₅₀H₆₂Fe₂N₁₀O₄
• 分子量: 978.801
• InChiKey: YEPXNTKCBOHKBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 、 copper(II) bis(trifluoromethanesulfonate) 以 1,4-二氧六环 、 水 为溶剂， 生成 、 、 、
  参考文献：
  名称：

  pH‐Driven Cu ²⁺ Translocation in Ferrocene‐Containing Ligands

  摘要：

  AbstractThe ligands L1H4, L2H2, and L3H4 have been synthesized, featuring two, one, and two ferrocene‐functionalized diamino‐diamido compartments, respectively. The coordination chemistry of the ligands towards Cu2+ has been fully characterized by means of potentiometric and spectrophotometric titrations, which allowed us to determine the protonation constants of the ligands, the formation constants of their complexes, and their coordination geometry. L1H4 and L2H2 feature additional diaminopyridine and bis(aminoquinoline) binding sites, respectively, and are capable of the pH‐driven translocation of two and one Cu2+ cations, respectively. Electrochemical experiments (CV) coupled with pH‐metric titrations demonstrate that while the coordination of Cu2+ to the compartments more distant from ferrocene (Fc), i.e. diaminopyridine in L1H4 and bis(aminoquinoline) in L2H2 leaves the oxidation potential of Fc unchanged, the translocation of the Cu2+ cation(s) inside the diamino‐diamido compartment(s) is signaled by a peculiar lowering of the Fc oxidation potential. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

  DOI：

  10.1002/ejic.200600607
• 作为产物：
  描述：

  吡啶-2,6-二甲醛 、 N(1),N(3)-bis(2-aminoethyl)-2-(ferrocenylmethyl)malonamide 、 二氯甲烷 在 NaBH₄ 作用下， 以 甲醇 、 乙腈 为溶剂， 以47.1%的产率得到
  参考文献：
  名称：

  pH‐Driven Cu ²⁺ Translocation in Ferrocene‐Containing Ligands

  摘要：

  AbstractThe ligands L1H4, L2H2, and L3H4 have been synthesized, featuring two, one, and two ferrocene‐functionalized diamino‐diamido compartments, respectively. The coordination chemistry of the ligands towards Cu2+ has been fully characterized by means of potentiometric and spectrophotometric titrations, which allowed us to determine the protonation constants of the ligands, the formation constants of their complexes, and their coordination geometry. L1H4 and L2H2 feature additional diaminopyridine and bis(aminoquinoline) binding sites, respectively, and are capable of the pH‐driven translocation of two and one Cu2+ cations, respectively. Electrochemical experiments (CV) coupled with pH‐metric titrations demonstrate that while the coordination of Cu2+ to the compartments more distant from ferrocene (Fc), i.e. diaminopyridine in L1H4 and bis(aminoquinoline) in L2H2 leaves the oxidation potential of Fc unchanged, the translocation of the Cu2+ cation(s) inside the diamino‐diamido compartment(s) is signaled by a peculiar lowering of the Fc oxidation potential. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

  DOI：

  10.1002/ejic.200600607