2a2-methoxy-3,6,9-tris(4-(trifluoromethyl)phenyl)-2,2a2,7,8-tetrahydro-1H-2a1,3a1,6a1-triaza-2a2l4-boratricyclopenta[cd,gh,kl]phenalen-6a1-ium | 1279035-31-2

• 英文名称: 2a2-methoxy-3,6,9-tris(4-(trifluoromethyl)phenyl)-2,2a2,7,8-tetrahydro-1H-2a1,3a1,6a1-triaza-2a2l4-boratricyclopenta[cd,gh,kl]phenalen-6a1-ium
• CAS: 1279035-31-2
• 化学式: C₃₇H₂₅BF₉N₃O
• 分子量: 709.422
• InChiKey: ZVFPVJYUEUCKHF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2a2-methoxy-3,6,9-tris(4-(trifluoromethyl)phenyl)-2a2H-2a1,3a1,6a1-triaza-2a2l4-boratricyclopenta[cd,gh,kl]phenalen-6a1-ium 在 Raney nickel 作用下， 以 四氢呋喃 为溶剂， 以39%的产率得到2a2-methoxy-3,6,9-tris(4-(trifluoromethyl)phenyl)-2,2a2,7,8-tetrahydro-1H-2a1,3a1,6a1-triaza-2a2l4-boratricyclopenta[cd,gh,kl]phenalen-6a1-ium
  参考文献：
  名称：

  Synthesis and Properties of Boron(III)-Coordinated Subbacteriochlorins

  摘要：

  Subbacteriochlorins, which were prepared via hydrogenation of subporphyrins with Raney nickel, are modestly aromatic due to 14 pi-diazaannulenic circuit and exhibit characteristic blue-shifted Soret-like bands, intensified fluorescence spectra, and high oxidation potentials.

  DOI：

  10.1021/ja200669a