Cu(N,N-diethylbenzhydrazide)Cl2 | 1130120-17-0

• 英文名称: Cu(N,N-diethylbenzhydrazide)Cl2
• CAS: 1130120-17-0
• 化学式: C₁₁H₁₆Cl₂CuN₂O
• 分子量: 326.713
• InChiKey: HJYHQQNFLOHKGP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cu(N,N-diethylbenzhydrazide)Cl2 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Crystal structures of two copper(II) complexes with N,N-diethylbenzhydrazide

  摘要：

  The copper(II) complexes with N,N-diethylbenzhydrazide, [Cu(C(6)H(5)CONHN(C(2)H(5))(2))]Cl(2) (I) and Cu(C(6)H(5)CONN(C(2)H(5))(2))(2) (II), have been studied by X-ray diffraction analysis. In the both compounds, the reactant acts as a bidentate (O, N(2)) ligand, forming five-membered chelate rings with copper. In cationic complex I, the O -> Cu and N -> Cu bond lengths are 1.954(2) and 2.070(3) A..., respectively, and the O(1)CuN(2) chelate angle is 81.89(10A degrees. The Cl(-) ions are in the coordination sphere of copper (Cu-Cl, 2.1974(11) and 2.2178(10) A...). The chelate ring has an envelope conformation with the copper atom in the flap position. The coordination polyhedron of the copper atom is a strongly distorted tetrahedron. Neutral complex II is an inner complex salt. The reactant forms with copper two planar chelate rings. The Cu-O and N -> Cu bond lengths are 1.8901(9) and 2.0175(11) A..., respectively, and the O(1)CuN(2) chelate cycle is 83.70(4)A degrees. Complex II is planar, and the coordination polygon of the copper atom is a parallelogram. The thermal stability of complexes I and II has been studied.

  DOI：

  10.1134/s0036023608010129
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 N',N'-diethylbenzohydrazide 以 乙醇 为溶剂， 生成 Cu(N,N-diethylbenzhydrazide)Cl2
  参考文献：
  名称：

  Crystal structures of two copper(II) complexes with N,N-diethylbenzhydrazide

  摘要：

  The copper(II) complexes with N,N-diethylbenzhydrazide, [Cu(C(6)H(5)CONHN(C(2)H(5))(2))]Cl(2) (I) and Cu(C(6)H(5)CONN(C(2)H(5))(2))(2) (II), have been studied by X-ray diffraction analysis. In the both compounds, the reactant acts as a bidentate (O, N(2)) ligand, forming five-membered chelate rings with copper. In cationic complex I, the O -> Cu and N -> Cu bond lengths are 1.954(2) and 2.070(3) A..., respectively, and the O(1)CuN(2) chelate angle is 81.89(10A degrees. The Cl(-) ions are in the coordination sphere of copper (Cu-Cl, 2.1974(11) and 2.2178(10) A...). The chelate ring has an envelope conformation with the copper atom in the flap position. The coordination polyhedron of the copper atom is a strongly distorted tetrahedron. Neutral complex II is an inner complex salt. The reactant forms with copper two planar chelate rings. The Cu-O and N -> Cu bond lengths are 1.8901(9) and 2.0175(11) A..., respectively, and the O(1)CuN(2) chelate cycle is 83.70(4)A degrees. Complex II is planar, and the coordination polygon of the copper atom is a parallelogram. The thermal stability of complexes I and II has been studied.

  DOI：

  10.1134/s0036023608010129