[Pd(2-CH2C6H4P(o-tolyl)2)(μ-Br)]2 | 172418-38-1

• 英文名称: [Pd(2-CH2C6H4P(o-tolyl)2)(μ-Br)]2
• CAS: 172418-38-1
• 化学式: C₄₂H₄₀Br₂P₂Pd₂
• 分子量: 979.375
• InChiKey: WBDUYBRZSRETCQ-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  [Pd(2-CH2C6H4P(o-tolyl)2)(μ-Br)]2 、 三吡唑啉基硼氢钾 以 丙酮 为溶剂， 以100%的产率得到Pd(2-CH2C6H4P(o-tolyl)2)(tris(pyrazol-1-yl)borate)
  参考文献：
  名称：

  Synthesis and reactivity of poly(pyrazol-1-yl)borate derivatives of cyclopalladation systems, including structural studies of Pd{2-CH2C6H4P(o-tolyl)2-C,P}{(pz)3BH-N,N′} and Pd(C6H4C5H4N-C2,N′){(pz)3BH-N,N′}

  摘要：

  The cyclopalladated complexes Pd{2-CH2C6H4P(o-tol)(2)}{(pz)(n)BH4-n} and Pd(C6H4C5H4N-(C)2, N){(pz)(n)BH4-n} [n = 2. 3: pz = pyrazol-1-yl] have been synthesised from the corresponding halide bridged cyclometallated dimers: the crystal structures of the complexes for which n = 3 have been determined. The complexes Pd{2-CH2C6H4P(o-tol)(2)}{(pz)(n)BH4-n} (n = 2, 3) and [Pd{2-CH2C6H4P(o-tol)(2)}(mu-O2CMe)](2) are unreactive towards oxidation by alkyl halides, iodobenzene and 4-bromoanisole. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00576-7