di-μ-[bis(5,5-dimethyl-1,3,2-dioxaphosphorinyl-2)resorcinol]bis(dichloroplatinum(II)) | 188903-41-5

• 英文名称: di-μ-[bis(5,5-dimethyl-1,3,2-dioxaphosphorinyl-2)resorcinol]bis(dichloroplatinum(II))
• CAS: 188903-41-5
• 化学式: C₃₂H₄₈Cl₄O₁₂P₄Pt₂
• 分子量: 1280.59
• InChiKey: OWSWFHNXTJNTCH-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 m-bis(5,5-dimethyl-1,3,2λ³-dioxaphosphorin-2-yloxy)benzene 以 二氯甲烷 为溶剂， 以95.6%的产率得到di-μ-[bis(5,5-dimethyl-1,3,2-dioxaphosphorinyl-2)resorcinol]bis(dichloroplatinum(II))
  参考文献：
  名称：

  Resorcinol bis(cyclophosphites)

  摘要：

  First representatives of resorcinol bis(cyclophosphites) were synthesized, on the basis of which a series of metallocomplexes, including a 16-membered binuclear metallocycle, was obtained. The fact that, in this system, two m-phenylene cycles are almost parallel with each other makes possible the creation of complex polynuclear constructions. The phosphocyclane rings in resorcinol bis(cyclophosphites) an readily opened by bromine and chloramine to form bis-(omega-halogenoallylphosphates) of resorcinol.

  DOI：

  10.1016/s0022-328x(96)06657-0