[Zn(2-(thiomethyl-2'-benzimidazolyl)benzimidazole)Br2] | 787630-00-6

• 英文名称: [Zn(2-(thiomethyl-2'-benzimidazolyl)benzimidazole)Br2]
• CAS: 787630-00-6
• 化学式: C₁₅H₁₂Br₂N₄SZn
• 分子量: 505.551
• InChiKey: XKHKKNFZXTZGEX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(((1H-benzo[d]imidazol-2-yl)methyl)-thio)-1H-benzo[d]imidazole 、 zinc dibromide 以 四氢呋喃 为溶剂， 以87%的产率得到[Zn(2-(thiomethyl-2'-benzimidazolyl)benzimidazole)Br2]
  参考文献：
  名称：

  Synthesis and Spectral Properties of the Complexes of Cobalt(II), Nickel(II), Copper(II), Zinc(II), and Cadmium(II) with 2‐(Thiomethyl‐2′‐benzimidazolyl)‐benzimidazole

  摘要：

  Synthesis of 2-(thiomethyl-2'-benzimidazolyl)benzimidazole (L) and its metal complexes of the formulae ML2(ClO4)(2) . xH(2)O (M = Co, x = 3; M = Ni, Zn, or Cd, x = 2; M = Cu, x = 1) and MLBr2 (M = Co, Ni, Cu, Zn, or Cd) are described. They have been characterized by measuring physical properties, IR, NMR, and electronic spectral studies. The electronic spectral and magnetic moment data Suggest an octahedral geometry for the cobalt(H) and nickel(11) perchlorate complexes, a tetrahedral geometry for the cobalt(II) and nickel(II) bromo complexes and a pseudo tetrahedral geometry for the copper(H) perchlorate and copper(H) bromide complexes. Based on elemental analyses, conductivity measurements and IR and NMR spectral Studies, a six-coordinate geometry for cadmium perchlorate complex and various four-coordinate geometries for zinc perchlorate and bromo complexes of cadmium and zinc have been proposed.

  DOI：

  10.1081/sim-120037514