[(bis(3,5-dimethyl-4-chloropyrazol-1-yl)methane)ZnBr2] | 194536-74-8

• 英文名称: [(bis(3,5-dimethyl-4-chloropyrazol-1-yl)methane)ZnBr2]
• CAS: 194536-74-8
• 化学式: C₁₁H₁₄Br₂Cl₂N₄Zn
• 分子量: 498.363
• InChiKey: XFSHBTIOMDPJDC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(3,5-dimethyl-4-chloropyrazole-1-yl)methane 、 zinc dibromide 以 乙醚 为溶剂， 以65%的产率得到[(bis(3,5-dimethyl-4-chloropyrazol-1-yl)methane)ZnBr2]
  参考文献：
  名称：

  Zinc(II), cadmium(II) and mercury(II) derivatives of bis(4-halopyrazol-1-yl)alkanes: synthesis, spectroscopic characterization and behaviour in solution

  摘要：

  The interaction between various bis(4-halopyrazol-1-yl)alkanes L (L* = bis(3,5-dimethyl-4-chloropyrazol-1 -yl)methane, L# = bis(4-bromopyrazol-1-yl)methane, L degrees = bis(4-chloropyrazol-1-yl)methane) and zinc(II), cadmium(II) and mercury(II) accepters gave 1:1 [LMX2] (L = L*, M = Zn, X = Cl, Br, I, NO3 or CF3CO2; L = L*, M = Cd, X = Cl Or Br; L I L*, M = Hg, X = Cl, Br or I; L = L#, Fvl = Zn, X = Cl, Br, I or NO,; L = L#, M = Cd, X = Cl, Br, I or NO3; L = L#, M = Hg, X = Cl or Br; L = L#, M = Zn, X = Cl, M = Cd, X = I, M = Hg, X = Br), 3:2 [(L*)(3)(Zn(CF3SO3)(2)}(2)].3H(2)O and [(L*)(3)(Cd(NO3)(2)}(2)].2H(2)O, 2: 1 [L,M]X, (L = L*, M = Zn or Cd, X = ClO4 or BF4; L = L*, M = Hg, X - ClO4; L = L#, M = Zn, X = ClO4 or CF3SO3, M = Cd, X = ClO4 or BF4; L degrees = L*, M = Cd, X = BF4) and finally 3:1 [(L#)(3)Zn](BF4)(2) adducts; these derivatives have been characterized through elemental analyses, spectral data (IR, H-1 and C-13 NMR in the case of the sufficiently soluble derivatives), conductivities and molecular weight measurements. Comparison is made with the results obtained with other bis(pyrazol-1-yl)alkanes. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00089-2