fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) | 17100-08-2

• 英文名称: fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I)
• 英文别名: fac-Mn(CO)3(hydride)(1,2-bis(diphenylphosphino)ethane)；fac-(CO)3(1,2-bis(diphenylphosphino)ethane)MnH；fac-Mn(CO)3(1,2-bis(diphenylphosphino)ethane)H；fac-[Mn(CO)3(PPh2(CH2)2PPh2)H]；fac-(CO)3(Ph2P(CH2)2PPh2)MnH；[(CO)3Mn(I)(1,2-bis(diphenylphosphino)ethane)(H)]
• CAS: 17100-08-2；36352-75-7
• 化学式: C₂₉H₂₅MnO₃P₂
• 分子量: 538.401
• InChiKey: FNKWGOIQCBNKIG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I) 、 氢溴酸 以 二氯甲烷 为溶剂， 生成 fac-[bromo(1,2-bis(diphenylphosphino)ethane)tricarbonylmanganese(I)]
  参考文献：
  名称：

  fac-（CO）3（PP）Mn-Z配合物的制备，反应和红外光谱（PP = DEPE，DPPE，DPPP; Z = H，OTs，OMe，OC（O）OMe，NCO，Cl，Br， N 3）

  摘要：

  一系列新的八面体Mn（I）配合物fac-（CO）3（depe）Mn-Z（depe = 1,2-双（二乙基膦基）乙烷，Z = H，OTs，OMe，OC（O）OMe，NCO ，Cl，Br，N 3）已经被制备和表征，特别是关于它们的红外光谱。与配位的一氧化碳有关的羰基拉伸频率中观察到的变化是Z基团的函数。这些光谱与类似的dppp，1，3-双（二苯基膦基）丙烷和dppe，1，2-双（二苯基膦基）乙烷络合物的相似光谱的比较显示了用苯基取代磷原子上的乙基的效果。Depe叠氮基络合物（Z = N 3）与炔烃反应生成三唑并合物，在与HCl水解后释放出三唑并再生生成叠氮基的氯配合物。

  DOI：

  10.1016/s0022-328x(97)00043-0
• 作为产物：
  描述：

  fac-Mn(CO)3(PPh2(CH2)2PPh2)(CHO) 以 氘代苯 为溶剂， 生成 fac-tricarbonyl(1,2-bis(diphenylphosphino)ethane)hydridomanganese(I)
  参考文献：
  名称：

  The synthesis and reactions of Mn and Re formyl complexes, fac-(PP)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3

  摘要：

  Treatment of the salts fac-[(P-P)M(CO)4][BF4] (M = Mn, Re; P-P = dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield. Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydrides, fac-(P-P)M(CO)3H. On treatment with methyl triflate or protic acids the formyls undergo expected disproportionation reactions; the X-ray crystal structure determination of one of the products, fac-(dppp)Mn(CO)3CH2OCH3, is reported.

  DOI：

  10.1016/0022-328x(94)88015-8

文献信息

• Aryldiazene, Aryldiazenido, and Hydrazine Complexes of Manganese. Preparation, Characterization, and X-ray Crystal Structures of [Mn(CO)₃(4-CH₃C₆H₄NNH){PPh(OEt)₂}₂]BF₄ and [Mn(CO)₃(NH₂NH₂){PPh(OEt)₂}₂]BPh₄ Derivatives
  作者：Gabriele Albertin、Stefano Antoniutti、Alessia Bacchi、Emilio Bordignon、Fabio Busatto、Giancarlo Pelizzi

  DOI：10.1021/ic9608612

  日期：1997.3.1

  Aryldiazene complexes [Mn(CO)(3)(ArN=NH)P(2)]BF(4) (1, 2) and [Mn(CO)(3)P(2)}(2)(&mgr;-HN=NArArN=NH)](BF(4))(2) (3, 4) [P = PPh(OEt)(2), PPh(2)OEt; Ar = C(6)H(5), 2-CH(3)C(6)H(4), 4-CH(3)C(6)H(4), 4-CH(3)OC(6)H(4); ArAr = 4,4'-C(6)H(4)C(6)H(4), 4,4'-(2-CH(3))C(6)H(3)C(6)H(3)(2-CH(3)), 4,4'-C(6)H(4)CH(2)C(6)H(4)] were prepared by reacting hydride species MnH(CO)(3)P(2) with the appropriate aryldiazonium

  芳基二氮杂配合物[Mn（CO）（3）（ArN = NH）P（2）] BF（4）（1、2）和[Mn（CO）（3）P（2）}（2）（＆mgr; -HN = NArArN = NH）]（BF（4））（2）（3，4）[P = PPh（OEt）（2），PPh（2）OEt; Ar = C（6）H（5），2-CH（3）C（6）H（4），4-CH（3）C（6）H（4），4-CH（3）OC（6 ）H（4）; ArAr = 4,4'-C（6）H（4）C（6）H（4），4,4'-（2-CH（3））C（6）H（3）C（6）H （3）（2-CH（3）），4,4'-C（6）H（4）CH（2）C（6）H（4）]是通过使氢化物MnH（CO）（3 ）P（2）与适当的芳基重氮阳离子在-80摄氏度的CH（2）Cl（2）或丙酮溶液中。化合物的特征在于IR，（1）H和（31）P NMR光谱（其中（15 ）N同位素取代），并确定单
• Reactions of dirhenium heptoxide with manganese(I) and rhenium(I) hydrido, alkoxo, methylcarbonato, carbonato-bridged, and methoxymethyl complexes. The X-ray structures of fac-(CO)3(dppp)MnOReO3 and fac-(CO)3(dppp)ReOReO3
  作者：Damon A. Brown、David M. Kimari、Anna M. Duzs-Moore、Theodore A. Budzichowski、Douglas M. Ho、Santosh K. Mandal

  DOI：10.1016/s0022-328x(02)01632-7

  日期：2002.9

  manganese(I) and rhenium(I) hydrido fac-(CO)3(PP)MH}, alkoxo fac-(CO)3(PP)MOR}, methylcarbonato fac-(CO)3(PP)MOC(O)OCH3}, carbonato-bridged [(CO)3(PP)M]2μ-OC(O)O} and methoxymethyl fac-(CO)3(PP)MCH2OCH3} complexes, where, R is CH3 or CH2CH3, PP is dppe 1,2-bis(diphenylphosphino)ethane} or dppp 1,3-bis(diphenylphosphino)propane}, yielded the corresponding perrhenato complexes, fac-(CO)3(PP)MOReO3

  再处理2 ö 7与锰（I）和铼（I）氢基 FAC - （CO）3，烷氧（PP）MH} FAC - （CO）3（PP）MOR}，methylcarbonato FAc-（CO）3（PP）MOC（O）OCH 3 }，羰基桥接的[（CO）3（PP）M] 2 μ-OC（O）O}和甲氧基甲基 FAc-（ CO）3（PP）MCH 2 OCH 3 }配合物，其中R为CH 3或CH 2 CH 3，PP为dppe 1,2-双（二苯基膦基）乙烷}或dppp 1,3-双（二苯基膦基）丙烷}，生成相应的perrhenato配合物FAc-（CO）3（PP）MOReO 3（1，M = Mn，PP= dppe; 2，M = Mn，PP= dppp; 3，M = Re，PP= dppe; 4，M = Re，PP= dppp），中等至极高的产量。所述perrhenato络合物已经光谱表征和的分子结构FAC
• Use of the aqua complex [ fac -Mn(CO) 3 (dppe)OH 2 ]BF 4 for the preparation of a series of fac -Mn(CO) 3 (dppe)Z and [ fac -Mn(CO) 3 (dppe)Z]BF 4 complexes. X-ray crystal structures of three representative examples
  作者：Thomas M. Becker、Jeanette A. Krause Bauer、Craig L. Homrighausen、Milton Orchin

  DOI：10.1016/s0022-328x(00)00130-3

  日期：2000.5

  (prepared by a simple two-step, high-yield synthesis) is readily replaced by the desired anionic ligand Z−, to give a six-coordinate neutral species fac-Mn(CO)3(dppe)Z. Examples of such complexes where ZONO2, CN, OMe, OC(O)OMe, and OS(O)2CF3 (OTf) are reported herein. Neutral ligands also replace the aqua ligand to give ionic complexes [fac-Mn(CO)3(dppe)Z]BF4. Examples where Z=2,6-dimethylphenyl (xylyl)

  在AQUA配体的标题配合物（通过简单的两步，高产率合成制备的）很容易通过所期望的阴离子配体ž取代- ，得到六配位的中性物质FAC -Mn（CO）3（DPPE） Z. 本文报道了其中Z ＝O ＝NO 2，CN，OMe，OC（O）OMe和OS（O）2 CF 3（OTf）的此类络合物的实例。中性配体还取代了水族配体，得到离子络合物[ FAc -Mn（CO）3（DPPE）Z] BF 4。本文还报道了Z ＝ 2，6-二甲基苯基（二甲苯基）异氰化物，乙腈，苄腈和丙烯腈的实例。FAc -Mn（CO）3的晶体结构（DPPE）NO 3（2），[ FAc -Mn（CO）3（DPPE）（二甲苯基-NC）] BF 4（7）和[ FAc-（CO）3 Mn（DPPE）（PhCN）] BF 4（9），报道。
• One-pot synthesis of fac-[Mn(CO)3(PP)Cl] from Mn2(CO)10, [PP] and chlorinated solvents: [PP] = 1,2-bis(diethylphosphino)ethane (depe), 1,2-bis(diphenylphosphino)ethane (dppe) or 1,3-bis(diphenylphosphino)propane (dppp). The X-ray crystal structure of fac-[Mn(CO)3(depe)Cl]
  作者：Guang Qing Li、Julian Feldman、Jeanette A. Krause、Milton Orchin

  DOI：10.1016/s0277-5387(96)00523-2

  日期：1997.4

  Abstract In a one-pot reaction, the three titled manganese chloride complexes were prepared by refluxing Mn2(CO)10 with (PP) in 2-chloroethanol for two hours. The new compounds were characterized by IR, 1H NMR, mass spectra and microanalyses. The X-ray crystal structure of fac-Mn(CO)3(depe)Cl is also reported.

  摘要在一锅法反应中，将Mn2（CO）10与（PP）在2-氯乙醇中回流2小时，制得了三种标题的氯化锰配合物。通过IR，1H NMR，质谱和显微分析对这些新化合物进行了表征。还报道了fac-Mn（CO）3（depe）Cl的X射线晶体结构。
• The preparation and reactions of the azides of fac-Mn(CO)3(P-P)N3. The X-ray crystal structures of fac-[Mn(CO)3(P-P)(OH2)]BF4, fac-Mn(CO)3(P-P)() [(P-P)=dppe and depe], and fac-[Mn(CO)3(depe)(PPh3)]BF4
  作者：Thomas M. Becker、Jeanette A. Krause-Bauer、Craig L. Homrighausen、Milton Orchin

  DOI：10.1016/s0277-5387(99)00161-8

  日期：1999.8

  A simple three-step, high-yield synthesis of the titled azides from Mn-2(CO)(10) and P-P is described involving the intermediate aqua complexes, fac-[Mn(CO)(3)(P-P)(H2O)]BF4, 3a,b. The aqua ligand is very labile; it is easily exchanged for D2O, PPh3, and NO2-. Crystal structures of the two titled aqua complexes and fac-[Mn(CO)(3)(depe)(PPh3)]BF4, 6a, are reported. The aqua complexes react instantaneously with aqueous NaN3 to give quantitative yields of the corresponding covalent azides which undergo the expected 1,3-dipolar additions with CF3CN to give the corresponding tetrazoles whose crystal structures are also reported. (C) 1999 Elsevier Science Ltd. All rights reserved.