| 192935-63-0

• CAS: 192935-63-0
• 化学式: C₄₆H₅₂MoN₄O₂₀P₂
• 分子量: 1138.82
• InChiKey: TVTMGJNTPZLFNH-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  N-Pyrrolyl Phosphines:  Enhanced π-Acceptor Character via Carboalkoxy Substitution

  摘要：

  A series of 3,4-dicarboethoxy-N-pyrrolyl phosphine ligands (R2P-NC4H2(CO2Et)(2)) is described. A number of techniques, including reaction calorimetry, infrared spectroscopy, and X-ray crystallography, demonstrate that these ligands are potent pi-acceptors and that the electronic substituent parameter chi(i) for the 3,4-(EtO2C)(2)C4H2N moiety is ca. 16, placing it in a position between fluorine and chlorine.

  DOI：

  10.1021/om970129q