[(silver(I))(2-isocyanopyridine)2]n(BF4)n | 1229036-39-8

• 英文名称: [(silver(I))(2-isocyanopyridine)2]n(BF4)n
• 英文别名: [(silver(I))(2-isocyanopyridine)]n(BF4)n
• CAS: 1229036-39-8
• 化学式: Ag*BF₄*2C₆H₄N₂
• 分子量: 402.895
• InChiKey: ZFPRUGKPPXQMIU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-异氰基吡啶 、 silver tetrafluoroborate 以 丙酮 为溶剂， 以46%的产率得到[(silver(I))(2-isocyanopyridine)2]n(BF4)n
  参考文献：
  名称：

  Supramolecular coordination polymers of silver(I) with 2-isocyanopyridine or 1,2-phenylenediisocyanide

  摘要：

  The silver(I) complexes [Ag{C(5)H(4)N(NC)}](n)(BF(4))(n) (1), [Ag{C(5)H(4)N(NC)}(2)](n)(BF(4))(n) (2), [Ag{C(6)H(4)(NC)(2)}](n)(BF(4))(n) (3), and [Ag{C(6)H(4)(NC)(2)}(2)](n)(BF(4))(n) (4) have been synthesized using different Ag: L ratios of 2-isocyanopyridine (or 2-pyridylisocyanide, CNPy-2) or 1,2-phenylenediisocyanide ligands. The polymeric complex 2 has been characterized by X-ray diffraction revealing a polymeric chain structure. Breaking the polymeric structure of [Ag{C(6)H(4)(NC)(2)}](n)(BF(4))(n) (3) with acetonitrile, the dimeric complex [Ag{(CN)(2)C(6)H(4))}(NC-Me)(2)](2)(BF(4))(2) (5) is formed, which has been also characterized by X-ray diffraction. (C) 2010 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2010.02.007