| 259676-23-8

• CAS: 259676-23-8
• 化学式: C₂₂H₂₀Mo₂S₃Te
• 分子量: 700.079
• InChiKey: ZXFWCBYREYZTEZ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  、 苯硫酚 以 苯 为溶剂， 以34%的产率得到
  参考文献：
  名称：

  Synthesis, optical nonlinearity and crystal structure of a novel mixed-chalcogen, thiolato-bridged complex [(η5-C5H5)2Mo2(μ-S)(μ-Te)(μ-SPh)2]

  摘要：

  A novel dimolybdenum complex in which the metal atoms are bridged by two different chalcogens and two thiolato ligands has been synthesised and structurally characterised. This complex shows a large third-order optical nonlinearity as measured by degenerate four-wave mixing with picosecond excitation at 532 nm. A hyperpolarisability (gamma) of 1.2 x 10(-30) esu has been obtained. The structure of the complex was established by the single-crystal X-ray diffraction method. It consists of a Mo-Mo unit, which is bridged by one S, one Te and two (SPh) groups. Each Mo atom also has a (eta(5)-C5H5) group attached to it. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00648-8