1-ferrocenyltetracyanoanthraquinodimethane | 893417-65-7

• 英文名称: 1-ferrocenyltetracyanoanthraquinodimethane
• CAS: 893417-65-7
• 化学式: C₃₀H₁₆FeN₄
• 分子量: 488.331
• InChiKey: CHCADVGMSHYGEJ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-ferrocenylanthraquinone 、 丙二腈 在 β-alanine 、 TiCl₄ 作用下， 以 吡啶 为溶剂， 生成 1-ferrocenyltetracyanoanthraquinodimethane
  参考文献：
  名称：

  Directly-linked intramolecular donor–acceptor compounds of ferrocene and tetracyanoanthraquinodimethane

  摘要：

  Two new intramolecular donor-acceptor species have been prepared linking ferrocene (Fc) directly to either the 1 (1) or 2 (2) positions of tetracyanoanthraquinodimethane (TCNAQ). Spectroscopic and electrochemical characterisation show significant differences between 1 and 2, revealing the importance of the position of attachment. The Fc part is a poorer donor and the TCNAQ part a poorer acceptor than the respective parent molecules and an intramolecular charge-transfer transition is observed at 604 nm (1) and 634 nm (2). The X-ray structure of 1 shows the TCNAQ component with the typical folded conformation with the ferrocene unit rotated by 38.0 degrees relative to the ring to which it is attached. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2005.06.011