| 221661-63-8

• CAS: 221661-63-8
• 化学式: C₁₆H₁₂Cl₃MnN₂O₂
• 分子量: 425.58
• InChiKey: RSKKYWIRIKIURX-OCMVVAPRSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 manganese (II) acetate tetrahydrate 、 lithium chloride 以 乙醇 为溶剂， 以82%的产率得到
  参考文献：
  名称：

  Zeolite-encapsulated manganese(III)salen complexes

  摘要：

  Manganese(III) complexes of [N,N'-ethylenebis(salicylidene-aminato)] (salen), [N, N'-ethylenebis(5-chloro-salicylidene aminato)] (Cl-2 Salen), [N, N'-ethylenebis(5-bromo-salicylidene-aminato)] (Br-2 Salen) and [N, N'-ethylenebis(5-nitro-salicylidene-aminato)] [(NO2)(2)Salen] have been encapsulated in the supercages of zeolite X by the zeolite synthesis method. The catalysts have been characterized by FTIR, UV-Vis and EPR spectroscopic techniques, XRD, SEM, thermal and elemental analysis, as well as nitrogen adsorption and cyclic voltammetric studies. The extent of encapsulation of the Mn(III)Salen complexes in zeolite X varies with the nature of the substituent group on the aromatic ring. While bromo groups enhance encapsulation, substitution with -NO2, groups decreases the amounts of Mn(III) complexes encapsulated in the cavities of the zeolites. Cyclic voltammetric data indicate that the zeolite matrix facilitates the reduction of Mn(III) to Mn(ll), suggesting that it behaves like an electron-withdrawing substituent. The aerobic oxidation of styrene to benzaldehyde, styrene oxide and phenylacetaldehyde over these catalysts is also reported. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(97)00307-5