[Ag(ClO4)(bis(diphenylarsino)methane)]2 | 844466-72-4

• 英文名称: [Ag(ClO4)(bis(diphenylarsino)methane)]2
• 英文别名: [Ag(ClO4)(dpam)]2
• CAS: 844466-72-4
• 化学式: C₅₀H₄₄Ag₂As₄Cl₂O₈
• 分子量: 1359.22
• InChiKey: QMVOSUHTSWSWME-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  乙醇 、 [Ag(ClO4)(bis(diphenylarsino)methane)]2 以 乙醇 为溶剂， 以84%的产率得到[Ag(ClO4)(bis(diphenylarsino)methane)(MeCN)(EtOH)]2
  参考文献：
  名称：

  Syntheses, spectroscopic and structural characterization of some (solvated) binuclear adducts of the form Ag(oxyanion):dpem(:S) (1:1(:x))2 (oxyanion=ClO4, F3CCO2, F3CSO3; dpem=Ph2E(CH2)EPh2 (E=P, As))

  摘要：

  Syntheses, spectroscopic (IR, NMR and ESI MS) and single crystal X-ray structural characterizations are reported for a wide variety of adducts of Ag(oxyanion):dpem (:S) (1:1(: n))(2) (oxyanion = ClO4, F3CCO2 (tfa) F3CSO3 ffs); dpem = Ph2E(CH2)EPh2) stoichiometry among which the basic Ag(Ph-2(CH2)EPh2)(2)Ag core is diversely perturbed by interactions with anions and solvent molecules. ESI MS and P-31 NMR spectroscopy indicated that dinuclear species also exist in solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.032
• 作为产物：
  描述：

  二(1,2-二苯基偶砷基)甲烷 、 silver perchlorate 以 乙醇 、 乙腈 为溶剂， 以72%的产率得到[Ag(ClO4)(bis(diphenylarsino)methane)]2
  参考文献：
  名称：

  Syntheses, spectroscopic and structural characterization of some (solvated) binuclear adducts of the form Ag(oxyanion):dpem(:S) (1:1(:x))2 (oxyanion=ClO4, F3CCO2, F3CSO3; dpem=Ph2E(CH2)EPh2 (E=P, As))

  摘要：

  Syntheses, spectroscopic (IR, NMR and ESI MS) and single crystal X-ray structural characterizations are reported for a wide variety of adducts of Ag(oxyanion):dpem (:S) (1:1(: n))(2) (oxyanion = ClO4, F3CCO2 (tfa) F3CSO3 ffs); dpem = Ph2E(CH2)EPh2) stoichiometry among which the basic Ag(Ph-2(CH2)EPh2)(2)Ag core is diversely perturbed by interactions with anions and solvent molecules. ESI MS and P-31 NMR spectroscopy indicated that dinuclear species also exist in solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.032