[(1,4-bis(diphenylphosphino)butane)Pd(μ-butane-1,4-dithiolate)Rh(1,5-cyclooctadiene)]ClO4 | 200009-30-9

• 英文名称: [(1,4-bis(diphenylphosphino)butane)Pd(μ-butane-1,4-dithiolate)Rh(1,5-cyclooctadiene)]ClO4
• CAS: 200009-30-9
• 化学式: C₄₀H₄₈P₂PdRhS₂*ClO₄
• 分子量: 963.677
• InChiKey: BUOKQMSPQQRCAT-NSNKXZTFSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(cyclooctadiene)rhodium(I) perchlorate 、 cis-[Pd(butane-1,4-dithiolate)(1,4-bis(diphenylphosphino)butane)] 以 二氯甲烷 为溶剂， 以69%的产率得到[(1,4-bis(diphenylphosphino)butane)Pd(μ-butane-1,4-dithiolate)Rh(1,5-cyclooctadiene)]ClO4
  参考文献：
  名称：

  Mononuclear Platinum(II) and Palladium(II) Dithiolate Complexes as Chelate Metalloligands for Preparation of Heterobimetallic d⁸−d⁸ Complexes

  摘要：

  Palladium-rhodium and platinum-rhodium heterobimetallic bridged dithiolate complexes of general formula [(P-P)M(mu-S-S)Rh(COD)]ClO4 (COD = 1,5-cyclooctadiene. For M = Pt: P-P = (PPh3)(2) and S-S = EDT2- (1,2-ethanedithiolate) (1), PDT2- (1,3-propanedithiolate) (2), and BDT2-(1,4-buthanedithiolate) (3); P-P = dppb (1,4-bis(diphenylphosphino)butane) and S-S = EDT2- (4), PDT2- (5), and BDT2- (6); P-P = dppp (1,3-bis(diphenylphosphino)propane) and S-S = EDT2-(7), PDT2- (8), and BDT2- (9), For M = Pd: P-P = dppb and S-S = EDT2- (10), PDT2- (11), and BDT2- (12); P-P = dppp and S-S = EDT2- (13), PDT2- (14), and BDT2- (15)) have been prepared. The crystal structures for complexes 1-3, 6, 9, and 12 ha iie been determined, and hinged structures were found with angles between local coordination planes MS2Rh ranging from 111.27 degrees for complex 1 to 151.34 degrees for complex 3. Metal-metal distances show nonbonding interactions between metals. X-ray data for 1: triclinic, P (1) over bar, a = 11311(6) Angstrom, b = 12.991(6) Angstrom, c = 16.140(6) Angstrom, alpha = 84.86(6)degrees, beta = 75.73(6)degrees, gamma = 86.43(6)degrees, Z = 2, R = 0.0427 (R-w = 0.1151). X-ray data for 2: triclinic, P (1) over bar, a = 11.084(5) Angstrom, b = 13.094(6) Angstrom, c = 16.338(6) Angstrom, or 86.06(6)degrees, beta = 75.67(6)degrees, gamma = 88.55(6)degrees, Z = 2, R = 0.0470 (R-w = 0.1264). X-ray data for 3: orthorhombic, Pbca, a = 14.439(6) Angstrom, b = 19.807(6) Angstrom, c = 38.156(6) Angstrom, Z = 8, R = 0.0864 (R-w = 0.2457). X-ray data for 6: monoclinic, P2(1)/c, a = 20.338(6) Angstrom, b = 14.227(6) Angstrom, c = 14.570(6) Angstrom, beta = 100.94(6)degrees, Z = 4, R = 0.0536 (R-w = 0.1449). X-ray data for 9: monoclinic, P2(1)/c, a = 20.326(6) Angstrom, b = 14.109(6) Angstrom, c = 14.368(6) Angstrom, beta = 100.90(6)degrees, Z = 4, R = 0.0380 (R-w = 0.0990). X-ray data for 12: monoclinic, P2(1)/c, a =20.365(6) Angstrom, b = 14.156(6) Angstrom, c = 14.592(6) Angstrom, beta = 101.04(6)degrees, Z = 4, R = 0.0507 (R-w = 0.1500).

  DOI：

  10.1021/ic970557o