[(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Me)Cp] | 950685-52-6

• 英文名称: [(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Me)Cp]
• CAS: 950685-52-6
• 化学式: C₃₅H₄₉AlN₂
• 分子量: 524.769
• InChiKey: CPCSYPLMQOMCIC-IEBALEEYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Me)Cp] 、 水 以 水 为溶剂， 生成 [((2,6-(isopropyl)2C6H3)NC(CH3)CHC(CH3)N(2,6-(isopropyl)2C6H3))Al(methyl)OH]
  参考文献：
  名称：

  New route to alkylaluminum hydroxides via hydrolysis of cyclopentadienylaluminum complexes

  摘要：

  A novel, very simple and effective synthetic method for the formation of alkylaluminum complexes with terminal hydroxy group via hydrolysis of cyclopentadienylaluminum compounds has been found. Investigations of the hydrolysis of cyclopentadienylaluminum complexes (L)Al(Me)Cp (1) and (L)Al(Et)Cp (2) (L = HC[(CMe)(2,6-'Pr(2)C(6) H(3)N)](2)) have shown that the reaction leads to the formation of (L)AI(Me)OH (3) and (L)AI(Et)OH (4), respectively. The high selectivity of the hydrolysis was revealed. The crystal structures of 1, 2 and 4 were determined. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.05.045
• 作为产物：
  描述：

  (Me)AlCp2 、 2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene 以 甲苯 为溶剂， 以74%的产率得到[(HC((CMe)(2,6-(isopropyl)2C6H3N))2)Al(Me)Cp]
  参考文献：
  名称：

  New route to alkylaluminum hydroxides via hydrolysis of cyclopentadienylaluminum complexes

  摘要：

  A novel, very simple and effective synthetic method for the formation of alkylaluminum complexes with terminal hydroxy group via hydrolysis of cyclopentadienylaluminum compounds has been found. Investigations of the hydrolysis of cyclopentadienylaluminum complexes (L)Al(Me)Cp (1) and (L)Al(Et)Cp (2) (L = HC[(CMe)(2,6-'Pr(2)C(6) H(3)N)](2)) have shown that the reaction leads to the formation of (L)AI(Me)OH (3) and (L)AI(Et)OH (4), respectively. The high selectivity of the hydrolysis was revealed. The crystal structures of 1, 2 and 4 were determined. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.05.045