| 218799-62-3

• CAS: 218799-62-3
• 化学式: C₂₄H₄₀Cl₂KLaO₂
• 分子量: 609.49
• InChiKey: CSYZQEWXDIJTIC-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  、 以 四氢呋喃 为溶剂， 以13%的产率得到1,2-dihydropyren-2-ide;lanthanum(3+);oxolane;1,2,3,4,5-pentamethylcyclopenta-1,3-diene
  参考文献：
  名称：

  Synthesis and Properties of Lanthanum- Pyrene Complexes—Structure of [(Cp*La)3(μ-Cl)3(thf)(μ-η2:η6:η6-C16H10)], the First Complex with a Pyrene Trianion

  摘要：

  Different bonding modes are characteristic for the lanthanum centers of the title compound, a trinuclear lanthanum-pyrene complex in which an arene trianion is present for the first time (see picture for the structure). Thus, La1 and La3 reside in a tetrahedral environment, the La2 center in a distorted trigonal-bipyramidal one.

  DOI：

  10.1002/(sici)1521-3773(19981102)37:20<2886::aid-anie2886>3.0.co;2-g