tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-iodo-dimolybdate(I)(Mo-Mo) | 223131-31-5

• 英文名称: tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-iodo-dimolybdate(I)(Mo-Mo)
• CAS: 223131-31-5
• 化学式: C₁₆H₃₆N*C₁₈H₁₀IMo₂O₆S₂
• 分子量: 947.659
• InChiKey: LIANWMWBRJHGNR-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  、 四丁基碘化铵 以 丙酮 为溶剂， 生成 tetrabutylammonium bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-iodo-dimolybdate(I)(Mo-Mo)
  参考文献：
  名称：

  A mixed tribridging dimolybdenum(I) compound, bis(μ-benzenethiolato-S:S)hexacarbonyl-μ-iodo-dimolybdenum(I)(Mo—Mo)

  摘要：

  In the structure of the complex anion of the title compound, (C16H36N)[Mo2I(C6H5S)(2)(CO)(6)], two Mo atoms are linked by three bridging ligands (one I and two benzenethiolate), forming an Mo2I(C6H5S)(2) core. The Mo2S2 unit, with a mean Mo-S distance of 2.475 (2) Angstrom and a mean Mo-S-Mo angle of 71.21(4)degrees, is approximately planar. Relative to this Mo2S2 unit, the two benzene rings are in a syn configuration. The Mo-I distances are 2.9460(6) and 2.9599 (6) Angstrom, the Mo-Mo distance is 2.8824(7) Angstrom and the Mo-I-Mo angle is 58.43 (2)degrees.

  DOI：

  10.1107/s0108270198012025