| 445290-78-8

• CAS: 445290-78-8
• 化学式: C₁₄H₁₂Fe₂O₆Si
• 分子量: 416.025
• InChiKey: SCMZLLIWZVALDG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二甲基一氯硅烷 、 在 triethylamine 作用下， 以 乙醚 为溶剂， 以88%的产率得到[Cp(OC)2Fe]2Si(OSiMe2H)2
  参考文献：
  名称：

  Hydroxysilylene-Bridged Dinuclear Iron Complexes [Cp(OC)₂Fe]₂Si(X)OH (X = H, Cl, OH):  Synthesis, Structural Characterization, and Condensation with Chlorodimethylsilane

  摘要：

  The novel bis(ferrio)silanols [Cp(OC)(2)Fe](2)Si(X)OH [X = H (2), OH (4), Cl (7)] are obtained via hydrolysis of [Cp(OC)(2)Fe](2)Si(H)Cl (1) or via oxygenation of the bis(ferrio)hydridosilanes [Cp(OC)(2)Fe](2)Si(H)X [X = Cl (1), H (6)] with dimethyldioxirane. Subsequent condensation reactions with chlorodimethylsilane yield the bis(ferrio)siloxanes [Cp(OC)(2)Fe](2)Si(X)(OSiMe2H) [X = H (12), OSiMe2H (13), OH (15)]. In an analogous manner the hetero-bismetalated silanol [Cp(OC)(2)Fe][Cp(OC)(2)(Me3P)W]Si(Me)OH (11) and the disiloxane [Cp(OC)(2)Fe][Cp(OC)(2)-(Me3P)W] Si(Me)(OSiMe2H) (14) have been prepared. The influence of the transition metal substituents on the chemical and spectroscopic properties of these compounds has been investigated. The X-ray structure analyses of the bis(ferrio)silanol [Cp(OC)(2)Fe](2)Si(H)OH and the bis(ferrio)dimethoxysilane [Cp(OC)(2)Fe](2)Si(OCH3)(2) (5)-generated via methanolysis of [Cp(OC)(2)Fe](2)SiCl2 (3)-are presented.

  DOI：

  10.1021/om020193u
• 作为产物：
  描述：

  [(η5-cyclopentadienyl)Fe(CO)2]2SiCl2 、 水 在 KOH 作用下， 以 四氢呋喃 为溶剂， 以0%的产率得到
  参考文献：
  名称：

  Hydroxysilylene-Bridged Dinuclear Iron Complexes [Cp(OC)₂Fe]₂Si(X)OH (X = H, Cl, OH):  Synthesis, Structural Characterization, and Condensation with Chlorodimethylsilane

  摘要：

  The novel bis(ferrio)silanols [Cp(OC)(2)Fe](2)Si(X)OH [X = H (2), OH (4), Cl (7)] are obtained via hydrolysis of [Cp(OC)(2)Fe](2)Si(H)Cl (1) or via oxygenation of the bis(ferrio)hydridosilanes [Cp(OC)(2)Fe](2)Si(H)X [X = Cl (1), H (6)] with dimethyldioxirane. Subsequent condensation reactions with chlorodimethylsilane yield the bis(ferrio)siloxanes [Cp(OC)(2)Fe](2)Si(X)(OSiMe2H) [X = H (12), OSiMe2H (13), OH (15)]. In an analogous manner the hetero-bismetalated silanol [Cp(OC)(2)Fe][Cp(OC)(2)(Me3P)W]Si(Me)OH (11) and the disiloxane [Cp(OC)(2)Fe][Cp(OC)(2)-(Me3P)W] Si(Me)(OSiMe2H) (14) have been prepared. The influence of the transition metal substituents on the chemical and spectroscopic properties of these compounds has been investigated. The X-ray structure analyses of the bis(ferrio)silanol [Cp(OC)(2)Fe](2)Si(H)OH and the bis(ferrio)dimethoxysilane [Cp(OC)(2)Fe](2)Si(OCH3)(2) (5)-generated via methanolysis of [Cp(OC)(2)Fe](2)SiCl2 (3)-are presented.

  DOI：

  10.1021/om020193u