| 110337-70-7

• CAS: 110337-70-7
• 化学式: C₁₈H₂₀Cl₂N₂O₂Pd
• 分子量: 473.695
• InChiKey: JZRGZRUSMVBUSF-SKTPHEQHSA-L

反应信息

• 作为反应物：
  描述：

  以 四氢呋喃 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Dinuclear diimine palladium(II) and platinum(II) hydroxo and amido complexes: synthesis and X-ray crystal structures

  摘要：

  Treatment of L2MCl2 with AgBF4 in wet tetrahydrofuran (THF)-CH2Cl2 or wet CH2Cl2-ethanol yields the dinuclear palladium(II) and platinum(II) hydroxo complexes [L2M(mu-OMe)](2)(BF4)(2) (L-2 = diimine, M = Pd, Pt). Reaction of the dihydroxo bridged complexes with aromatic amines (ArNH2,) yields the corresponding diamido bridged complexes [L2M(mu-NHAr)](2)(BF4)(2). [L2M(mu-OH)](2)(BF4)(2) is unstable in methanol and converts to [M( CL-OMe)](2)(BF4)(2) The structures of several of these complexes were determined by single crystal X-ray diffraction and show the expected edge-shared square-planar Pt centers with bridging hydroxo, methoxo, or amido groups. Attempts to deprotonate the hydroxo and amido complexes were not successful. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00338-1