[Zr(6,6-dimethylcyclohexadienyl)(PMe3)(CO)(cyclopentadienyl)] | 805315-15-5

• 英文名称: [Zr(6,6-dimethylcyclohexadienyl)(PMe3)(CO)(cyclopentadienyl)]
• CAS: 805315-15-5
• 化学式: C₁₇H₂₅OPZr
• 分子量: 367.583
• InChiKey: KUZUBKNRDGLCEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(trimethylphosphine)(cyclopentadienyl)(6,6-dimethylcyclohexadienyl)zirconium 、 一氧化碳 以 正己烷 为溶剂， 以52%的产率得到[Zr(6,6-dimethylcyclohexadienyl)(PMe3)(CO)(cyclopentadienyl)]
  参考文献：
  名称：

  Reactions of Zr(C5H5)(6,6-dmch)(PMe3)2 and Zr(6,6-dmch)2(PMe3)2 (dmch=dimethylcyclohexadienyl) with CO and alkynes

  摘要：

  The reactions of Zr(C5H5)(6,6-dmch)(PMe3)(2) and Zr(6,6-dmch)(2)(PMe3)(2) (dmch = dimethylcyclohexadienyl) with CO lead to the selective replacement of one PMe3 ligand by CO. Both carbonyl complexes have been structurally characterized. Additionally, the reaction of the latter complex with PhC2SiMe3 leads to a similar replacement of one PMe3 ligand, involving simple coordination of the alkyne, rather than any coupling to the dmch ligand. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.04.012