[Cd(hydroxyl methoxy-di(2-pyridyl)methane anion)(thiocyanate)]4 | 919077-72-8

• 英文名称: [Cd(hydroxyl methoxy-di(2-pyridyl)methane anion)(thiocyanate)]4
• 英文别名: [Cd(dpk-OMe)(NCS)]4
• CAS: 919077-72-8
• 化学式: C₅₂H₄₄Cd₄N₁₂O₈S₄
• 分子量: 1542.9
• InChiKey: VIXBXIDXVGEFLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硫氰酸铵 、 甲醇 、 2-二吡啶基酮 、 cadmium(II) nitrate tetrhydrate 以 甲醇 为溶剂， 以32.7%的产率得到[Cd(hydroxyl methoxy-di(2-pyridyl)methane anion)(thiocyanate)]4
  参考文献：
  名称：

  Synthesis and structural characterization of tetranuclear cubane-like cadmium complex containing di-2-pyridyl ketone ligands

  摘要：

  Reaction of Cd(NO3)(2) center dot 4H(2)O and NH4SCN with dpk (dpk = di-2-pyridyl ketone) in CH3OH afforded a novel cubane-like polynuclear complex [Cd(dpk-OMe)(NCS)](4), 1, [dpk-OMe = anion of the hydroxyl methoxy-di(2-pyridyl)methane] has been characterized by X-ray structural analysis. The unprecedented monoanion ligand dpk-OMe [dpk-OMe = anion of the hydroxyl methoxy-di(2-pyridyl)methane] was prepared by dpk in methanolic solution. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.02.009