dimethylsilanediyl(1-indenyl)(2-methyl-4-phenyl-1-indenyl)zirconium chloride | 169466-85-7

• 英文名称: dimethylsilanediyl(1-indenyl)(2-methyl-4-phenyl-1-indenyl)zirconium chloride
• CAS: 169466-85-7
• 化学式: C₂₇H₂₄Cl₂SiZr
• 分子量: 538.703
• InChiKey: TXJMHWDIEHYTSV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  1H-inden-1-yl-dimethyl-(2-methyl-4-phenyl-1H-inden-1-yl)silane 、 氯化锆(IV) 在 正丁基锂 作用下， 以 甲苯 为溶剂， 以26%的产率得到dimethylsilanediyl(1-indenyl)(2-methyl-4-phenyl-1-indenyl)zirconium chloride
  参考文献：
  名称：

  New bridged zirconocenes for olefin polymerization: Binuclear and hybrid structures1Dedicated to Professor Dr. Gottfried Huttner on the occasion of his 60th birthday.1

  摘要：

  Four newly synthesized bridged bisindenyl zirconocenes which are derivatives of known structures have been tested in polymerizations of liquid propylene with methylaluminoxane as cocatalyst. They include two asymmetric and two binuclear systems which are suitable for isotactic polymerization. Surprising differences from the behavior of similar systems (regiospecificity, chain termination) are found and discussed. (C) 1998 Published by Elsevier Science B.V.

  DOI：

  10.1016/s1381-1169(97)00181-7