| 357980-83-7

• CAS: 357980-83-7
• 化学式: C₁₅H₂₅GaN₂
• 分子量: 303.1
• InChiKey: PIILLRWUTZSNGW-MVLPLDLRSA-N

反应信息

• 作为反应物：
  描述：

  、 N,N-二甲基苯铵四(五氟苯基)硼酸盐 以 further solvent(s) 为溶剂， 生成 μ-hydroxo-bis[[N-isopropyl-2-(isopropylamino)troponimino-N,N'](methyl)gallium(II)]tetrakis(pentafluorophenyl)borate
  参考文献：
  名称：

  A cationic hydroxo-bridged dinuclear gallium complex

  摘要：

  The crystal structure of mu -hydroxo-bis{[N-isopropyl-2-(isopropylamino)troponimino-N,N'](methyl)gallium(II)} tetrakis(pentafluorophenyl)borate (troponimine is 2,4,6-cycloheptatrien-1-imine), [Ga-2(C14H22N2)(2)(OH)]B(C6H5)(4), is discussed. The two (Pr-i(2)-ATI)GaMe (ATI is aminotroponimime) units of the dinuclear cation are linked by a bridging hydroxo group and are both slightly twisted from planarity.

  DOI：

  10.1107/s0108270100013962

文献信息

• Main-Group-Metal Chlorobenzene Complexes
  作者：Andrey V. Korolev、Fabien Delpech、Samuel Dagorne、Ilia A. Guzei、Richard F. Jordan

  DOI：10.1021/om010395a

  日期：2001.8.1

  Stable group 13 metal chlorobenzene complexes of general type [(Pr-i(2)-ATI)MR][B(C6F5)(4)](ClPh) (M = Al, Ga, In; Pr-i(2)-ATI = N,N ' -diisopropylaminotroponiminate) have been isolated. X-ray crystallographic studies show that the PhCl ligands in these compounds are coordinated by dative M-ClPh bonding and suggest that pi -stacking interactions between the PhCl phenyl ring and the iPr2-ATI ligand may also contribute to the PhCl coordination.