bis[μ-[2-[[(4-hydroxy-κO)butyl]-imino-κN]methyl-phenolato(2-)-κO]]diphenyldiboro | 264146-20-5

• 英文名称: bis[μ-[2-[[(4-hydroxy-κO)butyl]-imino-κN]methyl-phenolato(2-)-κO]]diphenyldiboro
• CAS: 264146-20-5
• 化学式: C₃₄H₃₆B₂N₂O₄
• 分子量: 558.293
• InChiKey: YGSIEBTWLNYNAC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N-(4-Hydroxybutyl)-salicylidenamin 、 苯硼酸 以 苯 为溶剂， 以75%的产率得到bis[μ-[2-[[(4-hydroxy-κO)butyl]-imino-κN]methyl-phenolato(2-)-κO]]diphenyldiboro
  参考文献：
  名称：

  Two new complexes of phenylboronic acid with N-salicylidene-4-aminobutanol

  摘要：

  The tridentate ligand N-salicylidene-4-aminobutanol (6) was obtained by condensation of salicylaldehyde with 4-aminobutanol and reacted with phenylboronic acid to afford either the dimeric structure, bis[mu-[2-[[(4-hydroxy-kappa O)butyl]imino-kappa N]methyl-pheno-lato(2-)-kappa O]]diphenyldiboro (7) or the monomeric derivative, 2-phenylbenzo[j]-8-aza-1,3-dioxa-2-boracycloundeca-8-ene (8), depending on the reaction conditions. The monomeric structure is a [5.4.0] heterobicycle boronate and has been analyzed by X-ray crystallography. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00477-6