| 355855-01-5

• CAS: 355855-01-5
• 化学式: C₃₆H₅₄N₂Th
• 分子量: 746.876
• InChiKey: VWGJBGSAJFWZRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 二氧化碳 以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Bis(permethylindenyl) Complexes of Thorium:  Synthesis, Structure, and Reactivity

  摘要：

  A variety of thorium complexes incorporating the bulky permethylindenyl ligand (Ind* = C9Me7) have been synthesized and characterized. Specifically, the dichloride Ind*2ThCl2 is obtained by reaction of ThCl4 with Ind*Li, from which Ind*2ThMe2, Ind*Th-2(NMe2)(2), Ind*(2)-Th(NC4H4)(2), and Ind*Th-2(eta (3)-H3BH)(2) may be obtained by metathesis with MeLi, LiNMe2, LiNC4H4, and Ca(BH4)(2), respectively. In contrast to simple metathesis, reaction of Ind*(2)-ThCl2 with KN(SiMe3)(2) yields the metallacyde Ind*Th-2(eta (2)-CH2SiMe2NSiMe3). X-ray diffraction studies on Ind*2ThCl2, Ind*2ThCl(mu -Cl)(2)Li(tmeda), Ind*2ThMe2, Ind*Th-2(NMe2)(2), Ind*(2)-Th(eta (2)-CH2SiMe2NSiMe3), and Ind*Th-2(eta (3)-H3BH)(2) indicate that the permethylindenyl ligands in these complexes exhibit a variety of conformations.

  DOI：

  10.1021/om010233e
• 作为产物：
  描述：

  bis(permethylindenyl)thorium dichloride 、 lithium dimethylamide 以 苯 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  Bis(permethylindenyl) Complexes of Thorium:  Synthesis, Structure, and Reactivity

  摘要：

  A variety of thorium complexes incorporating the bulky permethylindenyl ligand (Ind* = C9Me7) have been synthesized and characterized. Specifically, the dichloride Ind*2ThCl2 is obtained by reaction of ThCl4 with Ind*Li, from which Ind*2ThMe2, Ind*Th-2(NMe2)(2), Ind*(2)-Th(NC4H4)(2), and Ind*Th-2(eta (3)-H3BH)(2) may be obtained by metathesis with MeLi, LiNMe2, LiNC4H4, and Ca(BH4)(2), respectively. In contrast to simple metathesis, reaction of Ind*(2)-ThCl2 with KN(SiMe3)(2) yields the metallacyde Ind*Th-2(eta (2)-CH2SiMe2NSiMe3). X-ray diffraction studies on Ind*2ThCl2, Ind*2ThCl(mu -Cl)(2)Li(tmeda), Ind*2ThMe2, Ind*Th-2(NMe2)(2), Ind*(2)-Th(eta (2)-CH2SiMe2NSiMe3), and Ind*Th-2(eta (3)-H3BH)(2) indicate that the permethylindenyl ligands in these complexes exhibit a variety of conformations.

  DOI：

  10.1021/om010233e