Aggregation of lithium and mixed thallium(I)–lithium amides through η3- and η6-π-arene interactions in the solid
作者:Konrad W. Hellmann、Christian Galka、Lutz H. Gade、Thomas Kottke、Dietmar Stalke
DOI:10.1039/a708139a
日期:——
The mixed LiâTl amide [C10H6N[Li(thf)2]SiMe3}N(Tl)SiMe3}] has been synthesized and shown to aggregate via η6-areneâthallium coordination in the solid; a related pattern of aggregation is found for the partially solvated homometallic Li amide [C10H6N[Li(thf)]SiMe3}N(Li)SiMe3}] which displays an unusual η3-areneâlithium interaction.