((CO)6Fe2Se2)2(μ-C(H)-C(3-thienyl)) | 254762-16-8

• 英文名称: ((CO)6Fe2Se2)2(μ-C(H)-C(3-thienyl))
• CAS: 254762-16-8
• 化学式: C₁₈H₄Fe₄O₁₂SSe₄
• 分子量: 983.517
• InChiKey: XXFCCQAPBFFROQ-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  3-乙炔基噻吩 、 (μ-Se2)(carbonyl)6diiron 在 sodium acetate 作用下， 以 甲醇 为溶剂， 以48%的产率得到(CO)6Fe2(μ-SeC(H)=C(3-thienyl)Se)
  参考文献：
  名称：

  Acetylenic bond reduction anchored on (CO)6Fe2(μ-Se2): synthesis and characterization of [(CO)6Fe2{μ-SeC(H)C(R)Se}] and [{(CO)6Fe2Se2}2{μ-C(H)–C(R)}] (R=3-Th, 2-Th; Th=C4H3S)

  摘要：

  Thiopheneacelylene (RC=CH; R=3-Th, 2-Th; Th=C4H3S) adds across the Se-Se bond of (CO)(6)Fe-2(mu-Se-2) at room temperature in methanol solvent containing sodium acetate to yield the adduct (CO)(6)Fe-2{mu-SeC(H)=C(R)Se} (R = 3-Th (1); 2-Th (3)) and the double butterfly complex [{(CO)(6)Fe2Se2}(2){mu-C(H)-C(R)}] (R = 3-Th (2); 2-Th (4)). Compounds 1-4 were characterized by spectroscopic techniques (IR and H-1-,C-13- and Se-77-NMR) and their composition confirmed by elemental analysis. Structures of 2 and 4 were further confirmed by single-crystal X-ray diffraction study. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00420-9