[Pd[3,4-[O(CH2)2O]C6H2C(H)N(C6H11)-C6,N][((C6H5)2P)2CHCH2(N2C3H3)-P,P']][PF6] | 410096-31-0

• 英文名称: [Pd[3,4-[O(CH2)2O]C6H2C(H)N(C6H11)-C6,N][((C6H5)2P)2CHCH2(N2C3H3)-P,P']][PF6]
• CAS: 410096-31-0
• 化学式: C₄₄H₄₄N₃O₂P₂Pd*F₆P
• 分子量: 960.184
• InChiKey: LKOLPAXYNAWIOJ-HDAWDTCISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  咪唑 、 以 苯 为溶剂， 生成 [Pd[3,4-[O(CH2)2O]C6H2C(H)N(C6H11)-C6,N][((C6H5)2P)2CHCH2(N2C3H3)-P,P']][PF6]
  参考文献：
  名称：

  Cyclopalladated Complexes with Functionalized Diphosphines via Activation of Chelated 1,1-Bis(diphenylphosphino)ethene

  摘要：

  The reaction of 1 with 1,1-bis(diphenylphosphino)ethene (vdpp) gave the mononuclear cyclometalated compound 2. The withdrawing effect of the cyclopalladated moiety suffices to polarize the C=CH2 double bond to afford the addition products 3-8, by treatment of complex 2 with primary aliphatic and aromatic amines. The molecular structures of 2, 4, and 8 have been determined by X-ray crystallography, showing that the C-C distance in 4 and 8 has the expected single-bond length upon addition.

  DOI：

  10.1021/om0106884