ZnCl2(1-(2-pyridyl)benzotriazole) | 1227069-31-9

• 英文名称: ZnCl2(1-(2-pyridyl)benzotriazole)
• CAS: 1227069-31-9
• 化学式: C₂₂H₁₆Cl₂N₈Zn
• 分子量: 528.719
• InChiKey: GAQXKPSXSFFKMH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1-(2-吡啶基)苯并三唑 、 zinc(II) chloride 以 甲醇 、 甲苯 、 乙酰丙酮 为溶剂， 以53%的产率得到ZnCl2(1-(2-pyridyl)benzotriazole)
  参考文献：
  名称：

  Zinc and cadmium complexes of pyridyl-benzotriazole: Syntheses, structures and supramolecular interaction

  摘要：

  Five novel complexes with two pyridine substituted benzotriazole ligands, 1-(2-pyridyl)benzotriazole (L1) and 1-(4-pyridyl)benzotriazole (L2), [Zn(L-1)(2)Cl-2](1), [{Zn(L-1)(2)Cl-2} (C)(L1)2](2), [Zn(L-2)(2)Cl-2](3), [{Zn(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O] (4), and [{Cd(L2)(H2O)(3)(mu(2)-SO4)}center dot H2O](5) were synthesized. The details of the structures were characterized by X-ray single crystal analysis, revealing that these complexes were assembled together via supramolecular interaction, such as, hydrogen bonding and pi-pi interactions. The influence of organic ligands, anions and reaction conditions in the formation of the complexes were investigated. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.12.060