[RuCl2(CH3CN)(1,4,7-trimethyl-1,4,7-triazacyclononane)](CF3SO3) | 457885-14-2

• 英文名称: [RuCl2(CH3CN)(1,4,7-trimethyl-1,4,7-triazacyclononane)](CF3SO3)
• CAS: 457885-14-2
• 化学式: CF₃O₃S*C₁₁H₂₄Cl₂N₄Ru
• 分子量: 533.385
• InChiKey: YUIUEAYNHRNDOY-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Ru(1,4,7-trimethyl-1,4,7-triazacyclononane)Cl3 、 silver trifluoromethanesulfonate 、 乙腈 以 乙腈 为溶剂， 以80%的产率得到[RuCl2(CH3CN)(1,4,7-trimethyl-1,4,7-triazacyclononane)](CF3SO3)
  参考文献：
  名称：

  Solvolysis Products of the Types [RhMeL ₂ (Me ₃ [9]aneN ₃ )] ²⁺ and [RuCl _3—X L _X (Me ₃ [9]aneN ₃ )] ^(x)+ (x = 1‐2) and Preparation and Structure of [Ru([9]aneS ₃ )(Me ₃ [9]aneN ₃ )](CF ₃ SO ₃ ) ₂

  摘要：

  Solvolysis of [RhMe(CF3SO3)(2)(Me-3[9]aneN(3))] (1) (Me-3[9]aneN(3) = 1,4,7-trimethyl-1,4,7-triazacyclononane) in CH3CN, DMSO or pyrazole (L) leads to substitution of both trifluoromethylsulfonate ligands and formation of the cationic complexes [RhMeL2(Me-3[9]aneN(3))](CF3SO3)(2) 3-5. In contrast, treatment of [RuCl3(Me-3[9]aneN(3))] (2) with Ag(CF3SO3) in a 1:3 ratio for 2h in CH3CN leads to formation of the tetranuclear complex [{RuCl3(Me-3[9]aneN(3))}(2)Ag-2(CF3SO3)(CH3CN)](CF3SO3) (.) CH3CN (6) with a novel [(RuCl3)(2)Ag-2] core. More forcing conditions enable the substitution of respectively one or two chloride ligands by CH3CN (reflux 18h) or DMF (85degreesC, 1h) to afford [RuCl,(CH3CN)(Me-3[9]aneN(3))](CF3SO3) (7) and [RuCl(DMF)(2)(Me-3[9]aneN(3))](CF3SO3)(2) (8). The heteroleptic sandwich complex [Ru([9]aneS(3))(Me-3[9]aneN(3))](CF3SO3)(2) (9) can be prepared by reduction of 2 with Zn powder in acetone in the presence of 3 equiv. of Ag(CF3SO3), followed by addition of [9]aneS(3) (1,4,7-trithiacy-clononane). The redox potential Edegrees(Ru3+/Ru2+) of +1.87 V vs NHE for 9 is only -0.12 V lower than that of the homoleptic complex [Ru([9]aneS(3))(2)](2+). Crystal structures are reported for 3-9.

  DOI：

  10.1002/1521-3749(200206)628:6<1366::aid-zaac1366>3.0.co;2-#