((2,6-(Et2NCH2)2C6H3)AlSe)2 | 289890-45-5

• 英文名称: ((2,6-(Et2NCH2)2C6H3)AlSe)2
• CAS: 289890-45-5
• 化学式: C₃₂H₅₄Al₂N₄Se₂
• 分子量: 706.691
• InChiKey: OGGUIIWRJSOBKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1′-(2-bromo-1,3-phenylene)-bis-(N,Ndiethylamine) 在 BuLi 作用下， 以 乙醚 、 正己烷 、 甲苯 为溶剂， 生成 ((2,6-(Et2NCH2)2C6H3)AlSe)2
  参考文献：
  名称：

  Syntheses and Structures of the Arylaluminum Chalcogenides (ArAlE)₂ (Ar = 2-(NEt₂CH₂)-6-MeC₆H₃, E = Se; Ar = 2,6-(NEt₂CH₂)₂C₆H₃, E = Se, Te)

  摘要：

  Two intramolecular stabilized arylaluminum dihydrides, {2-(NEt2CH2)-6-MeC6H3}AlH2 (1) and {2,6-(NEt2CH2)(2)C6H3}AlH2 (2), were prepared by reducing the corresponding dichlorides with an excess of LiAlH4 in diethyl ether. Reactions of 1 and 2 with elemental selenium afforded the dimeric arylaluminum selenides [{2-(NEt2CH2)-6-MeC6H3}AlSe](2) (3) and [{2,6-(NEt2CH2)(2)C6H3}AlSe](2) (4). Reaction of 2 with metallic tellurium gave the dimeric arylaluminum telluride [{2,6-(NEt2CH2)(2)C6H3}AlTe](2) (5). The possible reaction pathway is discussed, and molecular structures determined by single-crystal X-ray analyses are presented fur 3 and 5.

  DOI：

  10.1021/ic000255d