[RuCl₂(CO)(PCy₃)₂] | 52524-94-4

• 英文名称: [RuCl₂(CO)(PCy₃)₂]
• 英文别名: RuCl2(CO)(P(cyclohexyl)3)2
• CAS: 52524-94-4
• 化学式: C₃₇H₆₆Cl₂OP₂Ru
• 分子量: 760.854
• InChiKey: ZQTHZTQJDVJIQC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [RuCl₂(CO)(PCy₃)₂] 在 MoH((CH₃)2CNC₆H₃(CH₃)2)(N(CH(CH₃)2)C₆H₃(CH₃)2)2 作用下， 以 not given 为溶剂， 以0%的产率得到[Ru(C)(PCy3)2Cl2]
  参考文献：
  名称：

  Two Generalizable Routes to Terminal Carbido Complexes

  摘要：

  Desulfurization of the thiocarbonyl ligand in square pyramidal [Ru(CS)Cl2(PCy3)2] (1-S) via sulfur atom abstraction using [Mo(H)(eta2-Me2CNAr)(N[i-Pr]Ar)2] forms [Ru(C)Cl2(PCy3)2] (1) cleanly over several hours in benzene; isolated yield is 55%. Complex 1 is also formed in 87% isolated yield upon reaction of [Ru(CHR)(PCy3)2Cl2] (R = p-C6H4Me, 2; Ph, 3) with vinyl acetate in dichloromethane. Complex 1-S is re-formed quantitatively from 1 upon treatment with elemental sulfur in CH2Cl2, but is prepared most conveniently by treatment of crude [Ru(CS)Cl2(PPh3)2(OH2)] with excess PCy3 in toluene. Nearly quantitative conversion of 1 to [Ru(CO)Cl2(PCy3)2] (1-O) occurs upon addition of dimethyldioxirane solution in acetone to 1 dissolved in CH2Cl2 at ca. -90 degrees C.

  DOI：

  10.1021/ja0453735
• 作为产物：
  描述：

  以 氘代氯仿 为溶剂， 生成 [RuCl₂(CO)(PCy₃)₂]
  参考文献：
  名称：

  Deactivation of the Grubbs Carbene Complex [RuCl₂(CHPh)(PCy₃)₂] by Allylic Alcohols

  摘要：

  While the (hydroxymethyl)carbene complex [RuCl2(=CHCH2OH)(PCy3)(2)] (2), prepared by metathesis from [RuCl2(=CHPh)(PCy3)(2)] (1) and allyl alcohol, reacts in solution to give the carbonyl derivative [RuCl2(CO)(PCy3)(2)] (3), in the absence of solvent the methoxycarbene isomer [RuCl2(=CHOCH3)(PCy3)(2)] (4) is formed. The catalytic reaction of 1 with allyl alcohol affords, besides small amounts of ethene and acrolein, predominantly propionaldehyde; with 3-buten-2-ol and catalytic amounts of 1, 3-butanone is obtained exclusively.

  DOI：

  10.1021/om0210006

文献信息

• An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom
  作者：Maximilian Joost、Matthew Nava、Wesley J. Transue、Christopher C. Cummins

  DOI：10.1039/c7cc06516g

  日期：——

  intermediacy of the N-isocyanate OCN2A. Reaction of 1 with [RuCl2(CO)(PCy3)2] leads to [RuCl2(CO)(1)(PCy3)2] which decomposes unselectively: in the product mixture, the carbide complex [RuCl2(C)(PCy3)2] was detected. Upon heating in the solid state or in solution, 1 decomposes to A, N2 and cyanogen (C2N2) as substantiated using molecular beam mass spectrometry, IR and NMR spectroscopy techniques.

  作为由碳原子和两个稳定的中性离去基团组成的化合物的实例，已经合成了7-异氰基-7-氮杂二氮杂降冰片二烯，CN 2 A（1，A = C 14 H 10或蒽），并在光谱和结构上进行了合成表征。可以转移1的末端C原子：异丁烯腈与1反应生成一氧化碳，可能是通过N-异氰酸酯OCN 2 A的中间体。的反应1与将[RuCl 2（CO）（PCY 3）2]导致[RuCl 2（CO）（1）（PCy 3）2 ]选择性分解：在产物混合物中，检测到碳化物络合物[RuCl 2（C）（PCy 3）2 ]。在固态或在溶液中加热时，1分解为A，N 2和氰化物（C 2 N 2），如使用分子束质谱，IR和NMR光谱技术证实的那样。
• Multifunctional Ruthenium Catalysts:  A Novel Borohydride-Stabilized Polyhydride Complex Containing the Basic, Chelating Diphosphine 1,4-Bis(dicyclohexylphosphino)butane and Its Application to Hydrogenation and Murai Catalysis
  作者：Samantha D. Drouin、Dino Amoroso、Glenn P. A. Yap、Deryn E. Fogg

  DOI：10.1021/om010745t

  日期：2002.3.1

  [RuCl2(dcypb)(CO)](2) 2 (dcypb = 1,4-bis(dicyclohexylphosphino)butane) was prepared in high yield via phosphine exchange between dcypb and RuCl2(CO)(PPh3)(2)(DMF) (1). Reaction of 2 with 8 equiv of (KBHBu3)-Bu-s affords [fac-RuH3(CO)(dcypb)](-) (3), stabilized by interactions with a K+ counterion and an intact (KBHBu3)-Bu-s molecule in the third coordination sphere. Substantial ion pairing accounts for the stability and high hydrocarbon solubility of 3. Complex 3 effects reduction of benzophenone under unprecedentedly mild conditions, at 1 atm of H-2 in refluxing 2-propanol. It is also active for ortho, functionalization of benzophenone under 20 atm of ethylene. Stoichiometric experiments reveal facile formation of orthometalated RuH(CO)[OC(C6H4)(Ph)](dcypb) (5), an intermediate proposed in both types of catalysis. The catalytic activity of isolated 5 supports this hypothesis in the case of hydrogenation but not of Murai catalysis. The X-ray crystal structures of 3 and 5 are reported.
• Synthesis and characterization of some ruthenium phosphoniodithiocarboxylate complexes
  作者：Thomas R. Gaffney、James A. Ibers

  DOI：10.1021/ic00135a067

  日期：1982.5