[(EtMeHN)B8H11NHEt] | 327621-94-3

• 英文名称: [(EtMeHN)B8H11NHEt]
• CAS: 327621-94-3
• 化学式: C₅H₂₆B₈N₂
• 分子量: 200.763
• InChiKey: VYZKMLLVFDBIBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [(EtH2N)B8H11NHEt] 、 碘甲烷 在 NaH 作用下， 以 四氢呋喃 为溶剂， 以37%的产率得到[(EtMeHN)B8H11NHEt]
  参考文献：
  名称：

  Synthesis of N-substituted derivatives of the hypho-(amine)(amino)B8H11 system

  摘要：

  The chemistry of the hypho-(amine)(amino)B8H11 system is developed by the synthesis of several derivatives by three routes. [(Et2HN)B8H11NEt2] (4), characterised by single-crystal X-ray work, is prepared from the reaction between B9H13(SMe2) and Et2NH. Methylation of [(EtH2N)B8H11NHEt] (1) using NaH and Mel gives, successively, [(EtMeHN)B8H11NHEt] (5), [(EtMe2N)B8H11NHEt] (6) and [(EtMe2N)B8H11NMeEt] (7). Alternatively, a displacement reaction with NHEt2 on (1) or on [(MeH2N)B8H11NHMe] (2) yields [(Et2HN)B8H11NHEt] (8) or [(Et2HN)B(8)H(11)NHMel (9), and a displacement on (1) with pyridine yields [(C5H5N)B8H11NHEt] (10). Phosphine-containing derivatives [(Ph3P)B8H11NHEt] (11) and [(PhMe2P)B8H11NHEt] (12) can be isolated from interaction of (1) with PPh3, [RhCl(PPh3)(3)] or [PtCl2(PMe2Ph)(2)](.) (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00612-4