| 156429-18-4

• CAS: 156429-18-4；59030-43-2
• 化学式: C₅₈H₄₅Au₃MnO₄P₃
• 分子量: 1544.75
• InChiKey: BSTUVXAVSGGOOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Syntheses of gold-manganese and gold-rhenium clusters, [(Ph3PAu)3M(CO)4] and [(Ph3PAu)4M(CO)4]+ (M  Mn, Re), and the crystal structure of [(Ph3PAu)4Mn(CO)4]BF4

  摘要：

  The specific additions of one, three or four Ph3PAu groups to [M(CO)5]- (M = Mn, Re) are described. Thus [M(CO)5]- in THF reacts with [(Ph3PAu)3O]BF4 to give [(Ph3PAu)4Mn(CO)4]BF4. An X-ray crystal structure of the M = Mn example shows the cation to have a trigonal bipyramidal Au4Mn core with the Mn in an equatorial site. The previously known neutral (Ph3PAu)3M(CO)4 clusters are formed by addition of two Ph3PAu groups, using the mixed reagent [(Ph3PAu)3O]BF4/[ppn][Co(CO)4], to Ph3PAuM(CO)5, which itself is readily prepared from [M(CO)5]- and Ph3PAuCl.

  DOI：

  10.1016/0022-328x(92)80218-m
• 作为产物：
  描述：

  PPh₃Au^IC₈H₅ 、 、 isocyanato(triphenylphosphine)gold(I) 以 四氢呋喃 为溶剂， 以52.6%的产率得到
  参考文献：
  名称：

  Holzer, M.; Straehle, J., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：

文献信息

• Synthese und Kristallstruktur von (Ph₃PAu)₄[AuMn(CO)₅]₂ und (Ph₃PAu)₃Re(CO)₄/ Synthesis and Crystal Structure of (Ph₃PAu)₄ [AuMn(CO)₅]₂ and (Ph₃PAu)₃Re(CO)₄
  作者：Markus Richter、Dieter Fenske、Joachim Strähle

  DOI：10.1515/znb-2000-1004

  日期：2000.10.1

  The reaction of [Mn(CO)₅]^- with the cluster cation [(Ph₃PAu)₈]²⁺ in thf yields the heterometallic cluster [(Ph₃PAu)₄ [AuMn(CO)₅]₂ (1) as the main product besides small amounts of (Ph₃PAu)₃Mn(CO)₄. The former crystallizes as 1-thf in form of red blocks in the triclinic space group P1 with a = 1391,0( 1), b = 1426.7( 1), c = 2308.3(2) pm, α = 92.87(1), β = 97.54( 1), γ = 96.43(1)° and Z = 2. The inner Au₆ skeleton of the almost centrosymmetrical cluster consists of two Au₄ tetrahedra sharing one edge. Two gold atoms bind a Mn(CO)₅ fragment, whereas to the other four gold atoms phosphine ligands are coordinated. The Au-Au distances range from 263.2(1) to 281.9(1) pm, and the Au-Mn distances are 256.6(3) and 256.9(2) pm. By the reaction of [(Ph₃PAu)₈]²⁺ with [Re₂(CO)₉]^2- the cluster (Ph₃PAu)₃Re(CO)₄ (2) is obtained in low yield besides the homometallic cluster [(AuPPh₃)₇]⁺ as the main product. 2 crystallizes from toluene as 2 C₇H₈ in the form of yellow blocks with the orthorhombic space group Pna2₁, and a = 1758.7(3), b = 1648.7(5), c = 2049.3(5) pm. The four metal atoms form a planar lozenge with the Re atom in equatorial position. The Re-Au distances range from 271.2(1) to 273.7(1) pm, and the Au-Au distances are 278.2(1) and 278.4(1) pm

  摘要：在THF中[Mn(CO)₅]^-与团簇阳离子[(Ph₃PAu)₈]²⁺反应，除了少量的(Ph₃PAu)₃Mn(CO)₄，主要产物是异金属团簇[(Ph₃PAu)₄ [AuMn(CO)₅]₂ (1)。前者以1-THF的形式以红色块状物在三斜晶系空间群P1中结晶，其中a = 1391.0(1)，b = 1426.7(1)，c = 2308.3(2) pm，α = 92.87(1)，β = 97.54(1)，γ = 96.43(1)°，Z = 2。几乎中心对称团簇的内部Au₆骨架由两个共享一条边的Au₄四面体组成。两个金原子结合了一个Mn(CO)₅片段，而其他四个金原子则配位于膦配体上。Au-Au距离范围从263.2(1)到281.9(1) pm，Au-Mn距离分别为256.6(3)和256.9(2) pm。通过[(Ph₃PAu)₈]²⁺与[Re₂(CO)₉]^2-的反应，除了同金属团簇[(AuPPh₃)₇]⁺作为主要产物外，还得到了低产量的(Ph₃PAu)₃Re(CO)₄ (2)。2以黄色块状物的形式从甲苯中结晶，空间群为Pna2₁，a = 1758.7(3)，b = 1648.7(5)，c = 2049.3(5) pm。四个金属原子形成一个平面菱形，其中Re原子处于赤道位置。Re-Au距离范围从271.2(1)到273.7(1) pm，Au-Au距离分别为278.2(1)和278.4(1) pm。